화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.41, 91-104, September, 2016
Development of thermo-responsive poly(vinyl alcohol)-g-poly(N-isopropylacrylamide) copolymeric membranes for separation of isopropyl alcohol/water mixtures via pervaporation
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This study aims to develop thermo-responsive poly(N-isopropylacrylamide) (PNIPAAm) grafted poly(vinyl alcohol) (PVA-g-PNIPAAm) copolymer membranes for separation of isopropyl alcohol (IPA)/water mixtures via pervaporation. PVA-g-PNIPAAm copolymers were synthesized by microwavesupported graft copolymerization. Structure of copolymers was characterized by element analysis, FTIR, TGA/DTG/DSC, 13C NMR and SEC. PVA-g-PNIPAAm membranes prepared with casting technique were characterized by SEM-AFM. Effects of grafting yield, operation temperature, and feed concentration on separation factor and flux were investigated to determine the membrane performance. The maximum separation factor was 95 with flux of 0.011 kg/m2 h at 87.4% IPA. Thermo-responsive PVA-g-PNIPAAm membranes developed in this study are promising for pervaporation.
  1. Sajjan AM, Premakshi HG, Kariduraganavar MY, J. Ind. Eng. Chem., 25, 151 (2015)
  2. Uragami T, Morikawa T, Okuno H, Polymer, 30, 1117 (1989)
  3. Kahya S, Solak EK, Sanlı O, Vacuum, 84, 1092 (2010)
  4. Premakshi HG, Ramesh K, Kariduraganavar MY, Chem. Eng. Res. Des., 94, 32 (2015)
  5. Deng S, Shiyao B, Sourırajan S, Matsuura T, J. Colloid Interface Sci., 136, 283 (1990)
  6. Komorowska-Durka M, van Houten R, Stefanidis GD, Chem. Eng. Process., 81, 35 (2014)
  7. Zhang QG, Liu QL, Chen Y, Chen JH, Ind. Eng. Chem. Res., 46(3), 913 (2007)
  8. Salehian P, Chua ML, Askari M, Shi GM, Chung TS, J. Membr. Sci., 493, 299 (2015)
  9. Halake K, Birajdar M, Kim BS, Bae H, Lee CC, Kim YJ, Kim S, Kim HJ, Ahn S, An SY, Lee J, J. Ind. Eng. Chem., 20(6), 3913 (2014)
  10. Bano S, Mahmood A, Kim SJ, Lee KH, Sep. Purif. Technol., 137, 21 (2014)
  11. Wandera D, Wickramasinghe SR, Husson SM, J. Membr. Sci., 357(1-2), 6 (2010)
  12. Leal D, Borggraeve WD, Encinas MV, Matsuhiro B, Muller R, Carbohydr. Polym., 92, 157 (2013)
  13. Naidua BVK, Sairam M, Raju KVSN, Aminabhavi TM, J. Membr. Sci., 260(1-2), 142 (2005)
  14. Chiang WY, Chen CL, Polymer, 39(11), 2227 (1998)
  15. Yang CC, Li YJJ, Liou TH, Desalination, 276(1-3), 366 (2011)
  16. Rachipudi PS, Kariduraganavar MY, Kittur AA, Sajjan AM, J. Membr. Sci., 383(1-2), 224 (2011)
  17. Peters TA, Poeth CHS, Benes NE, Buijs HCWM, Vercauteren FF, Keurentjes JTF, J. Membr. Sci., 276(1-2), 42 (2006)
  18. Hilmioglu ND, Tulbentci S, Desalin. Water Treat., 48, 191 (2012)
  19. Yigitoglu M, Aydin G, Isiklan N, Polym. Bull., 71(2), 385 (2014)
  20. Akın A, Isıklan N, Int. J. Biol. Macromol., 82, 530 (2016)
  21. Isiklan N, Sanli O, J. Appl. Polym. Sci., 93(5), 2322 (2004)
  22. Isiklan N, Sanli O, Chem. Eng. Process., 44(9), 1019 (2005)
  23. Feng XS, Huang RY, Ind. Eng. Chem. Res., 36(4), 1048 (1997)
  24. Das P, Ray SK, Kuila SB, Samanta HS, Singha NR, Sep. Purif. Technol., 81(2), 159 (2011)
  25. Gurdag G, Oz GM, Polym. Adv. Technol., 20, 216 (2009)
  26. Fundueanu G, Constantin M, Ascenzi P, Acta Biomater., 6, 3899 (2010)
  27. Singha NR, Kar S, Ray S, Ray SK, Chem. Eng. Process., 48(5), 1020 (2009)
  28. Munoz FM, Ruiz JC, Lorenzo CA, Radiat. Phys. Chem., 81, 531 (2012)
  29. Guan HM, Chung TS, Huang Z, Chng ML, Kulprathipanja S, J. Membr. Sci., 268(2), 113 (2006)
  30. Ortiz HIM, Bucio E, Burillo G, Radiat. Phys. Chem., 78, 1 (2009)
  31. Isıklan N, Kucukbalcı G, Eur. J. Pharm. Biopharm., 82, 316 (2012)
  32. Olukman M, Sanli O, Chem. Eng. Process., 98, 60 (2015)
  33. Peresin MS, Vesterinen AH, Habibi Y, Johansson LS, Pawlak JJ, Nevzorov AA, Rojas OJ, J. Appl. Polym. Sci., 131, 40334 (2014)
  34. Jaiswal MK, Banerjee R, Pradhan P, Bahadur D, Colloids Surf. B: Biointerfaces, 81, 185 (2010)
  35. Tamura A, Kobayashi J, Yamato M, Okano T, Acta Biomater, 8, 3904 (2012)
  36. Park KC, Idota N, Tsukahara T, React. Funct. Polym., 79, 36 (2014)
  37. An Q, Li F, Ji Y, Chen H, J. Membr. Sci., 367(8), 158 (2011)
  38. Saeed A, Georget DMR, Mayes AG, React. Funct. Polym., 70(4), 230 (2010)
  39. Uriostegui LG, Burillo G, Bucio E, Radiat. Phys. Chem., 81, 295 (2012)
  40. Thakura VK, Thakurb MK, Gupta RK, Int. J. Biol. Macromol., 62, 44 (2013)
  41. Sajjan AM, Kumar BKJ, Kittur AA, Kariduraganavar MY, J. Ind. Eng. Chem., 19(2), 427 (2013)
  42. Ruckenstein E, Liang L, J. Membr. Sci., 110(1), 99 (1996)
  43. Moon GY, Pal R, Huang RYM, J. Membr. Sci., 156(1), 17 (1999)
  44. Bowen TC, Noble RD, Falconer JL, J. Membr. Sci., 245(1-2), 1 (2004)
  45. Nawawi MG, Huang RY, J. Membr. Sci., 124(1), 53 (1997)
  46. Han M, Zhao B, Zhang XM, Zhang WJ, Chem. Eng. Process., 47(2), 245 (2008)
  47. Yu J, Lee CH, Hong WH, Chem. Eng. Process., 41(8), 693 (2002)
  48. Lee CH, Hong WH, J. Membr. Sci., 135(2), 187 (1997)
  49. Shao P, Huang RYM, J. Membr. Sci., 287(2), 162 (2007)
  50. Kusumocahyo SP, Sudoh M, J. Membr. Sci., 161(1-2), 77 (1999)
  51. Al-Ghezawi N, Sanli O, Isiklan N, Sep. Sci. Technol., 41(13), 2913 (2006)
  52. Han CC, Wei TC, Wu CS, Liu YL, J. Membr. Sci., 358(1-2), 60 (2010)
  53. Uragami T, Shinomiya H, J. Membr. Sci., 74, 183 (1992)
  54. Hua D, Chung TS, J. Membr. Sci., 492, 197 (2015)
  55. Svang-Ariyaskul A, Huang RYM, Douglas PL, Pal R, Feng X, Chen P, Liu L, J. Membr. Sci., 280(1-2), 815 (2006)
  56. Murthy ZVP, Shah MK, Arab. J. Chem., http://dx.doi.org/10.1016/j.arabjc.2012.07.008 (in press). (2012)
  57. Muniz EC, Geuskens G, J. Membr. Sci., 172(1-2), 287 (2000)
  58. Zhang RN, Su YL, Peng JM, Fan XC, Jiang ZY, Zhao XT, Liu JZ, Li YF, Zhao JJ, Polymer, 55(6), 1347 (2014)
  59. Huang RYM, Yeom CK, J. Membr. Sci., 58, 33 (1991)
  60. Park JY, Jung HC, Raju GSR, Moon BK, Jeong JH, Choi HY, Kim JH, Ceram. Int., 39, 6599 (2013)
  61. Teli SB, Gokavi GS, Sairam M, Aminabhavi TM, Colloids Surf. A: Physicochem. Eng. Asp., 301, 55 (2007)
  62. Adoor SG, Sairam M, Manjeshwar LS, Raju KVSN, Aminabhavi TM, J. Membr. Sci., 285(1-2), 182 (2006)
  63. Toti US, Aminabhavi TM, J. Membr. Sci., 228(2), 199 (2004)
  64. Hilmioglu ND, Tulbentci S, Vacuum, 72, 35 (2004)