화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.36, 154-162, April, 2016
Synergistic effect of incorporating ZIF-302 and graphene oxide to polysulfone to develop highly selective mixed-matrix membranes for carbon dioxide separation from wet post-combustion flue gases
E-mail:
Graphene oxide (GO) nanosheets and zeolitic imidazole frameworks (ZIF-302) were synergistically integrated to glassy polysulfone (PSF) to fabricate mixed-matrix membranes (MMMs) to separate carbon dioxide from post-combustion flue gas stream. In order to optimize CO2 separation performance of composite membranes form dry and wet gases, both nanofillers in varying compositions were incorporated into PSF to prepare MMMs using solution-casting technique. The flexible MMMs rendered homogeneous dispersion of fillers, improved polymer-filler adhesion, and thermally stable structure. Gas sorption analyses along with dry and wet gas permeation experiments demonstrated improved CO2 permeability coupled with high CO2/N2 ideal selectivity of MMMs due to synergistic effect of nanofillers. The hybrid membrane containing 1 wt% GO and 30 wt% ZIF-302 nanofillers showed an optimum separation performance by providing a CO2 permeability of 13 Barrers with CO2/N2 ideal selectivity of 52. The permeation characteristics of hybrid membranes were found to be better than already existing membranes and were not affected by humid conditions.
  1. D’Alessandro DM, Smit B, Long JR, Angew. Chem.-Int. Edit., 49, 6058 (2010)
  2. Jacobson MZ, Energy Environ. Sci., 2, 148 (2009)
  3. MacDowell N, Florin N, Buchard A, Hallett J, Galindo A, Jackson G, Adjiman CS, Williams CK, Shah N, Fennell P, Energy Environ. Sci., 3, 1645 (2010)
  4. Herzog H, Golomb D, Encycl. Energy, 1, 277 (2004)
  5. Hussain A, Hagg MB, J. Membr. Sci., 359(1-2), 140 (2010)
  6. Zhao J, Wang Z, Wang JX, Wang SC, J. Membr. Sci., 283(1-2), 346 (2006)
  7. Pandey P, Chauhan RS, Prog. Polym. Sci, 26, 853 (2001)
  8. Mahajan R, Koros WJ, Ind. Eng. Chem. Res., 39(8), 2692 (2000)
  9. Fawas EP, Kapantaidakis GC, Nolan JW, Mitropoulos AC, Kanellopoulos NK, J. Mater. Process. Technol., 186, 102 (2007)
  10. Baker RW, Ind. Eng. Chem. Res., 41(6), 1393 (2002)
  11. Gin DL, Noble RD, Science, 332(6030), 674 (2011)
  12. Xiao Y, Chung TS, Energy Environ. Sci., 4, 201 (2011)
  13. Staudt-Bickel C, Koros WJ, J. Membr. Sci., 155(1), 145 (1999)
  14. Merkel TC, Freeman BD, Spontak RJ, He Z, Pinnau I, Meakin P, Hill A, Science, 296, 519 (2002)
  15. Ahn JY, Chung WJ, Pinnau I, Guiver MD, J. Membr. Sci., 314(1-2), 123 (2008)
  16. Reid BD, Ruiz-Trevino A, Musselman IH, Balkus KJ, Ferraris JP, Chem. Mater., 13, 2366 (2001)
  17. Kim S, Marand E, Ida J, Guliants VV, Chem. Mater., 18, 1149 (2006)
  18. Kim S, Marand E, Microporous Mesoporous Mater., 114, 129 (2008)
  19. Vu DQ, Koros WJ, Miller SJ, J. Membr. Sci., 211(2), 335 (2003)
  20. Cong HL, Zhang JM, Radosz M, Shen YQ, J. Membr. Sci., 294(1-2), 178 (2007)
  21. Kim S, Chen L, Johnson JK, Marand E, J. Membr. Sci., 294(1-2), 147 (2007)
  22. Gorgojo P, Uriel S, Tellez C, Coronas J, Microporous Mesoporous Mater., 115, 85 (2008)
  23. Liu Y, Peng D, He G, Wang S, Li Y, Wu H, Jiang Z, ACS Appl. Mater. Interfaces, 6, 13051 (2014)
  24. Harold B, Jeazet T, Staudt C, Janiak C, J. Chem. Soc.-Dalton Trans., 41, 14003 (2012)
  25. Ge L, Wang L, Rudolph V, Zhu Z, RSC Adv., 3, 25360 (2013)
  26. Zornoza B, Seoane B, Zamaro JM, Tellez C, ChemphysChem, 12, 2781 (2011)
  27. Valero M, Zornoza B, Tellez C, Coronas J, Microporous Mesoporous Mater., 192, 23 (2013)
  28. Galve A, Sieffert D, Staudt C, Ferrando M, Guell C, Tellez C, Coronas J, J. Membr. Sci., 431, 163 (2013)
  29. Li XQ, Ma L, Zhang HY, Wang SF, Jiang ZY, Guo RL, Wu H, Cao XZ, Yang J, Wang BY, J. Membr. Sci., 479, 1 (2015)
  30. Li T, Pan Y, Peinemann KV, Lai Z, J. Membr. Sci., 425-426(425), 235 (2013)
  31. Zhang C, Zhang K, Xu LR, Labreche Y, Kraftschik B, Koros WJ, AIChE J., 60(7), 2625 (2014)
  32. Askari M, Chung TS, J. Membr. Sci., 444, 173 (2013)
  33. Nhung TTN, Furukawa H, Gandara F, Nguyen HT, Cordova KE, Yaghi OM, Angew. Chem.-Int. Edit., 126, 10821 (2014)
  34. Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228 (2010)
  35. Yang H, Li F, Shan C, Han D, Zhang Q, Niu L, Ivaska A, Mater J, J. Mater. Chem., 19, 4632 (2009)
  36. Yang YH, Bolling L, Priolo MA, Grunlan JC, Adv. Mater., 25(4), 503 (2013)
  37. Kim H, Miura Y, Macosko CW, Chem. Mater., 22, 3441 (2010)
  38. Huang HD, Ren PG, Chen J, Zhang WE, Ji X, Li ZM, J. Membr. Sci., 409-410, 156 (2012)
  39. Zulhairun AK, Ismail AF, J. Membr. Sci., 468, 20 (2014)
  40. Bhole YS, Wanjale SD, Kharul UK, Jog JP, J. Membr. Sci., 306(1-2), 277 (2007)
  41. Hu HQ, Zhao L, Liu JQ, Liu Y, Cheng JM, Luo J, Liang YR, Tao Y, Wang X, Zhao J, Polymer, 53(15), 3378 (2012)
  42. Tian L, Meziani MJ, Lu F, Kong CY, Cao L, Thorne TJ, Sun YP, ACS Appl. Mater. Interfaces, 2, 3217 (2010)
  43. Ahn JY, Chung WJ, Pinnau I, Guiver MD, J. Membr. Sci., 314(1-2), 123 (2008)
  44. Nik OG, Chen XY, Kaliaguine S, J. Membr. Sci., 413-414, 48 (2012)
  45. Ahmad AL, Adewole JK, Leo CP, Sultan AS, Ismail S, J. Appl. Polym. Sci., 131, 40924 (2014)
  46. Paul DR, Kemp DR, J. Polym. Sci. Polym. Symp., 41, 79 (1973)
  47. Remyamol T, John H, Gopinath P, Carbon, 59, 308 (2013)
  48. Xiao YC, Chung TS, Guan HM, Guiver MD, J. Membr. Sci., 302(1-2), 254 (2007)
  49. Chang ACC, Chuang SSC, Gray M, Soong Y, Energy Fuels, 17(2), 468 (2003)
  50. Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)