화학공학소재연구정보센터
Combustion and Flame, Vol.165, 310-320, 2016
Raman scattering measurements of mixing and finite-rate chemistry in a supersonic reacting flow over a piloted, ramped cavity
UV Raman scattering is applied to measure fuel/air mixing and combustion of a Mach-2 air stream flowing over a step-ramp cavity fueled with 70% methane/30% hydrogen. Average and RMS fluctuations of temperature and major species profiles as well as scatter plots of simultaneous temperature and chemical scalars are determined from single-shot Raman scattering measurements along a 6-mm line transverse to the main supersonic flow. In the fuel-rich regions of the pilot cavity, the 248-nm KrF laser induces broadband fluorescence interference that reduces the number of analyzable Raman spectra; nonetheless, on the whole, a significant fraction of the spectra were reducible. In the cavity, hydrogen fuel reacts quickly resulting in a uniform water concentration in the recirculation zone. Methane reacts slowly to carbon monoxide/carbon dioxide in the cavity, leading to non-uniform concentrations of these species. Mean and instantaneous mixture fraction data inside the shear layer were indicative of oxygen transport across the shear layer. Temperature, water, and oxygen fluctuations are fairly constant throughout the combustor due to recirculation/turbulent transport across the shear layer and the slow reaction of methane. (C) 2015 The Combustion Institute. Published by Elsevier Inc. All rights reserved.