화학공학소재연구정보센터
Polymer, Vol.69, 159-168, 2015
Photocleavable epoxy based materials
The present study aims at the development of photodegradable epoxy based materials comprising o-nitrobenzyl ester links that undergo well defined bond cleavage in response to UV irradiation. New bifunctional epoxy based monomers bearing o-nitrobenzyl ester groups are synthesized and thermally cured with an anhydride hardener to yield photosensitive polymers and duromers. The UV induced changes in solubility are exploited for the preparation of positive-type photoresists. Thin patterned films are obtained by photolithographic processes and characterized by microscopic techniques. The results evidence that sensitive resist materials with good resolution and high contrast behavior can be accomplished. Along with resist technology, the applicability of o-nitrobenzyl chemistry in the design of recyclable polymer materials with thicknesses in the millimeter range is evaluated. By monitoring the thermo-mechanical properties upon UV illumination, a distinctive depletion of storage modulus and glass transition temperature is observed with increasing exposure dose. Additionally, single fiber pull-out tests are carried out revealing a significant decrease of the interfacial adhesion at the fiber-matrix interface due to the phototriggered cleavage reaction. (C) 2015 Elsevier Ltd. All rights reserved.