화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals, Vol.376, 135-140, 2002
Charge transfer degree of BO complexes
The accurate degree of charge transfer (CT) of BO complexes was obtained by Raman spectroscopy. A rich variety of states with partial CT in a wide range were available for BO materials, either due to stoichiometry or incomplete CT. Above certain acceptor strength, in the complex with BO there is a tendency for the acceptor to be ionized to the fully ionic state of -1 regardless the redox potential in general. The transport properties of BO complexes were discussed in terms of CT degree.