화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.40, No.48, 17371-17379, 2015
The role of the WO3 nanostructures in the oxygen reduction reaction and PEM fuel cell performance on WO3-Pt/C electrocatalysts
Oxygen reduction reaction (ORR) was investigated on carbon supported platinum and tungsten oxide nanoparticles generated by chemical reduction. The results were correlated with the surface properties of these electrocatalysts. X-ray Photoelectron Spectroscopy (XPS), High Resolution Transmission Electron Microscopy (HRTEM), Scanning Transmission Electron Microscopy (STEM), Energy Dispersive Spectroscopy (EDS) studies have been used to analyze the structure and surface properties of WO3-Pt/C electrocatalysts. The analysis of the platinum Pt 4f peak by XPS showed that this metal is present in the surface as Pt with some oxidized platinum pet while tungsten oxide is present as W6+. The XPS results showed the strong interaction between Pt and WO3. By electron microscopy techniques, it was observed that using this synthesis method, both, platinum and tungsten oxide are well dispersed on vulcan carbon, which may favor the formation of Pt WO3 interfaces. Thus, in comparison to conventional Pt/C, the 5%WO3-Pt/C electrocatalyst exhibited higher electrocatalytic activity toward the oxygen reduction reaction in a single cell polymer electrolyte membrane (PEM) fuel cell. However, with the incorporation of tungsten oxide at higher contents the WO, species are more dominating on the catalysts surface, reducing the accessibility of the reactants to the platinum active sites and therefore the electrochemical response in the ORR. Copyright (c) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.