화학공학소재연구정보센터
Fuel Processing Technology, Vol.138, 1-13, 2015
Devolatilization kinetics of swine manure solid pyrolysis using deconvolution procedure. Determination of the bio-oil/liquid yields and char gasification
In the present study, the pyrolysis process under dynamic conditions of swine manure solids collected from rearing farm was investigated. Tested type of biomass feedstock was analyzed from the point of view of technological exploitation in order to obtain the highest possible quality and yields of bio-oil and bio-char. Furthermore, char gasification process was also examined. It was found that pyrolysis process can be described by parallel independent two-portion process model (PI-TPPM), which includes two processing state of the system (marked by processes # 1 and # 2), where process # 1 can be attributed to decomposition processes of hemicelluloses and fats/proteins, while process # 2 corresponds to pyrolyses of cellulose and lignin. Also, it was found that liquid and gas yields increase with an increase in heating rate, while approximately 40% of heavy oil yield is achieved by proposed experimental setup, which have been attained the satisfactory results for a good support in industrial extraction procedures. It was found that results associated with the presence of high reactivity at highest heating rate can be attributed to the highly porous structures formed, as we approach to the fast pyrolysis conditions. (C) 2015 Elsevier B.V. All rights reserved.