화학공학소재연구정보센터
Electrochimica Acta, Vol.184, 143-150, 2015
LiFe1-x(Ni0.98Co0.01Mn0.01)(x)PO4/C (x=0.01, 0.03, 0.05, 0.07) as cathode materials for lithium-ion batteries
LiFe1-x(Ni0.98Co0.01Mn0.01)(x)PO4/C (x = 0.01, 0.03, 0.05, 0.07) is prepared by using spent electroless nickel plating solution as a raw material. The mechanism of the reaction is investigated by the analyses of thermogravimetric and differential scanning calorimeter (TG/DSC) and X-ray diffraction (XRD). It is found that the formation of LiFe1-x(Ni0.98Co0.01Mn0.01)(x)PO4/C starts at 300 degrees C, and above 500 degrees C, the product can be ascribed to LiFe1-x(Ni0.98Co0.01Mn0.01)(x)PO4/C. The structure, morphology and electrochemical properties of the samples are characterized by XRD, scanning electron microscope (SEM), electrochemical impedance spectroscopy(EIS) and charge/discharge tests. The results show that the Ni, Co and Mn multi-doping does not destroy the olivine structure of LiFePO4 and is beneficial to the uniform distribution of particles, which improves the electrochemical properties of the samples. Especially, LiFe0.97(Ni0.98Co0.01Mn0.01)(0.03)PO4/C exhibits the best cycling stability and rate capability among all the samples. Its initial discharge capacity is 150.6 mAh g(-1) with the capacity retention of 98.8% after 100 cycles at 1 C. Even at 10 C, it still shows a high discharge capacity of 116.5 mAh g(-1). (C) 2015 Elsevier Ltd. All rights reserved.