화학공학소재연구정보센터
Journal of Materials Science, Vol.29, No.15, 4119-4124, 1994
The Formation of Namg2Al15O25 in an Alpha-Al2O3 Matrix and Its Effect on the Mechanical-Properties of Alumina
An in-situ sintering reaction was designed to produce lath-like beta"’-alumina in an alpha-alumina matrix in order to make alumina ceramics stronger and tougher. The reaction sequence to produce beta"’-alumina (NaMg2Al15O25) requires the formation of beta-alumina (NaAl11O17) and spinel (MgAl2O4) at around 1100-degrees-C followed by a solid-state reaction of these two phases to give beta"’-alumina at elevated temperatures; this reaction is complete at around 1600-degrees-C. The in-situ sintering reaction produces near-theoretically dense alumina ceramics in which lath-like beta"’-aluminas are homogeneously distributed. The bending strength and fracture toughness increase to 620 M Pa and 5 M Pa m1/2, respectively; these increases are thought to be due to the suppression of grain growth as well as the crack deflection and bridging associated with lath-like beta"’-alumina.