화학공학소재연구정보센터
Catalysis Today, Vol.259, 228-236, 2016
Photocatalytic hydrophobic concrete coatings to combat air pollution
Several low cost, user-friendly photocatalytic surface coatings were applied to cementitious surfaces and tested as a remediation technique for transportation NO emissions and organic pollutants. All of the sols (aqueous suspensions of nanoparticles) coatings showed very high nitrogen oxide (NO) conversion (-90%) and Methylene Blue dye bleaching when applied to concrete surfaces, even when the coatings were extremely thin or diluted, independently on the deposition method ( spraying or dip coating). A novel hydrophobic coating based on photocatalyst nanoparticles suspended in a siloxane sealant showed similar conversion at low NO concentrations but required a greater loading of TiO2. At high NO concentrations the hydrophobic coating was less effective, even at greater TiO2 loadings, suggesting that the adsorption is the rate limiting step in this conversion process. A threshold of 1% TiO2 loading in hydrophilic coating and 5% in the case of hydrophobic was needed to obtain a quantitative NO conversion. A home-made TiO2 sol showed lower NO photodegradation but a more homogeneous and bonded layer. (C) 2015 Elsevier B.V. All rights reserved.