화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.30, 239-248, October, 2015
Development of electroless Ni.P modified aluminum substrates in a simulated fuel cell environment
E-mail:
The corrosion resistance of electroless Ni.P coating on pure Al, Al 6061, Al 3004 and Al 1050 is examined in an environment simulated to PEM fuel cell. Potentiodynamic polarization techniques, Interfacial contact resistance, surface morphology, chemical composition of coated substrates and EIS measurements have been investigated. Modified Al 1050 showed reduction in its corrosion current density by 44.69 times. It also showed the best stability of all modified Al substrates. The formed Ni.P layer on Al 1050 is thicker by about 3 times, relative to that on Al 6061 and has higher Ea value of 135.68 kJ mol-1 supporting its lower corrosion rate.
  1. Mehta V, Cooper JS, J. Power Sources, 114(1), 32 (2003)
  2. Costamagna P, Srinivasan S, J. Power Sources, 102(1-2), 242 (2001)
  3. Gottesfeld S, Zawodzinski TA, Adv. Electrochem. Sci. Eng., 5, 195 (1997)
  4. Lee SJ, Huang CH, Chen YP, J. Mater. Process. Technol., 140, 688 (2003)
  5. Lee SJ, Huang CH, Lai JJ, Chen YP, J. Power Sources, 131(1-2), 162 (2004)
  6. Kumar A, Ricketts M, Hirano S, J. Power Sources, 195(5), 1401 (2010)
  7. Dur E, Cora ON, Koc M, Int. J. Hydrog. Energy, 36(12), 7162 (2011)
  8. Sherif ESM, J. Ind. Eng. Chem., 19(6), 1884 (2013)
  9. Ehsani A, Nasrollahzadeh M, Mahjani MG, Moshrefi R, Mostaanzadeh H, J. Ind. Eng. Chem., 20(6), 4363 (2014)
  10. Singh A, Lin Y, Liu W, Yu S, Pan J, Ren C, Kuanhai D, J. Ind. Eng. Chem., 20(6), 4276 (2014)
  11. Awad MK, Metwally MS, Soliman SA, El-Zomrawy AA, bedair MA, J. Ind. Eng. Chem., 20(3), 796 (2014)
  12. Borup RL, Vanderborgh NE, Mater. Res. Soc. Symp. Proc., 393, 151 (1995)
  13. Barranco J, Barreras F, Lozano A, Maza M, J. Power Sources, 196(9), 4283 (2011)
  14. Schultze JW, Bressel A, Electrochim. Acta, 47(1-2), 3 (2001)
  15. Homma T, Komatsu I, Tamaki A, Nakai H, Osaka T, Electrochim. Acta, 47(1-2), 47 (2001)
  16. Takano N, Hosoda N, Yamada T, Osaka T, J. Electrochem. Soc., 146(4), 1407 (1999)
  17. Furukawa S, Mehregany M, Sens. Actuators A-Phys., 56, 261 (1996)
  18. Baudrand D, Durkin B, Met. Finish., 96, 20 (1998)
  19. Hong IK, Kim H, Lee SB, J. Ind. Eng. Chem., 20(5), 3767 (2014)
  20. Parkinson R, Properties and Applications of Electroless Nickel, in: Nickel Development Institute Technical Series 10081, 1997, p. 11.
  21. Soleimani R, Mahboubi F, Arman SY, Kazemi M, Maniee A, J. Ind. Eng. Chem., 23, 328 (2015)
  22. Golru SS, Attar MM, Ramezanzadeh B, J. Ind. Eng. Chem., 24, 233 (2015)
  23. Fetohi AE, Hameed RMA, El-Khatib KM, Souaya ER, Int. J. Hydrog. Energy, 37(9), 7677 (2012)
  24. Azumi K, Yugiri T, Seo M, Fujimoto S, J. Electrochem. Soc., 148(6), C433 (2001)
  25. Wang HL, Turner JA, J. Power Sources, 128(2), 193 (2004)
  26. Hatada K, J. Jpn. Inst. Electron. Packag., 8, 330 (2005)
  27. Saito M, Maegawa T, Homma T, Electrochim. Acta, 51(5), 1017 (2005)
  28. Guang-Xi L, Geng-Fu L, Fu-Chang Y, Wear, 103, 269 (1985)
  29. Ozyilmaz AT, Kardas G, Erbil M, Yazici B, Appl. Surf. Sci., 242(1-2), 97 (2005)
  30. Davis JR, Corrosion of Aluminum and Aluminum Alloys, first ed., ASM International (The Materials Information Society), 1999p. 34 (Chapter 2).
  31. Gao Y, Huang L, Zheng ZJ, Li H, Zhu M, Appl. Surf. Sci., 253(24), 9470 (2007)
  32. Bai CY, Chou YH, Chao CL, Lee SJ, Ger MD, J. Power Sources, 183(1), 174 (2008)
  33. Aal AA, Shaaban A, Hamid ZA, Appl. Surf. Sci., 254(7), 1966 (2008)
  34. Zhang WX, Jiang ZH, Li GY, Jiang Q, Lian JS, Surf. Coat. Technol., 202, 2570 (2008)
  35. Balaraju JN, Selvi VE, Grips VKW, Rajam KS, Electrochim. Acta, 52(3), 1064 (2006)
  36. Balaraju JN, Rajam KS, Surf. Coat. Technol., 195, 154 (2005)
  37. Gao Y, Zheng ZJ, Zhu M, Luo CP, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 381, 98 (2004)
  38. Lin JY, Lin CY, Liu SK, Wan CC, Wang YY, Surf. Coat. Technol., 205, 2251 (2010)
  39. Lu GJ, Zangari G, Electrochim. Acta, 47(18), 2969 (2002)
  40. Shibli SMA, Dilimon VS, Int. J. Hydrog. Energy, 32(12), 1694 (2007)
  41. Raicheff R, Zaprianova V, J. Mater. Sci. Lett., 19(1), 3 (2000)
  42. Bai A, Chuang PY, Hu CC, Mater. Chem. Phys., 82(1), 93 (2003)
  43. Okamoto Y, Nitta Y, Imanaka T, Teranishi S, J. Catal., 64, 397 (1980)
  44. Ashassi-Sorkhabi H, Rafizadeh SH, Surf. Coat. Technol., 176, 318 (2004)
  45. Flis J, Duquette DJ, Corrosion, 41, 700 (1985)
  46. Putilova IN, Balezin SA, Barannik VP, Metallic Corrosion Inhibitors, Pergamon Press, New York, NY, 1960p. 31.
  47. Tawfik H, Hung Y, Mahajan D, J. Power Sources, 163(2), 755 (2007)
  48. U.S. Department of Energy, The Hydrogen, Fuel Cells & Infrastructure Technologies Program Multi-year Research, Development and Demonstration Plan, U.S. Department of Energy, Washington, DC, 2005, http://www1.eere.energy.gov/hydrogenandfuelcells/mypp/pdfs/fuel_cells.pdf; February, p, 3-89.
  49. Tian RJ, Sun JC, Wang JL, Int. J. Hydrog. Energy, 33(24), 7507 (2008)
  50. Tian RJ, Sun JC, Wang L, J. Power Sources, 163(2), 719 (2007)
  51. Avasarala B, Haldar P, J. Power Sources, 188(1), 225 (2009)
  52. Fetohi AE, Hameed RMA, El-Khatib KM, Souaya ER, Int. J. Hydrog. Energy, 37(14), 10807 (2012)
  53. Tzeng SS, Chang FY, Thin Solid Films, 388(1-2), 143 (2001)
  54. Juttner K, Electrochim. Acta, 35, 1501 (1990)
  55. Patel AS, Panchal VA, Mudaliar GV, Shah NK, Saudi J, Chem. Soc., 17, 53 (2013)
  56. Turhan MC, Lynch R, Killian MS, Virtanen S, Electrochim. Acta, 55(1), 250 (2009)
  57. Liu C, Bi Q, Leyland A, Matthews A, Corrosion Sci., 45, 1243 (2003)
  58. Kerner Z, Pajkossy T, J. Electroanal. Chem., 448(1), 139 (1998)
  59. Kim CH, Pyun S, Kim JH, Electrochim. Acta, 48(23), 3455 (2003)
  60. Wang JT, Wang WW, Wang C, Mao ZQ, Int. J. Hydrog. Energy, 37(17), 12069 (2012)
  61. Ismail KM, Fathi AM, Badawy WA, Corrosion Sci., 48, 1912 (2006)
  62. Sapoval B, Solid State Ion., 75, 269 (1995)
  63. Nyikos L, Pajkossy T, Electrochim. Acta, 30, 1533 (1985)
  64. Osorio WR, Freitas ES, Garcia A, Electrochim. Acta, 108, 781 (2013)