화학공학소재연구정보센터
Journal of Crystal Growth, Vol.414, 32-37, 2015
Analysis of HVPE grown AlGaN layers on honeycomb patterned sapphire
Thick AlxGa1-xN layers were grown by hydride vapor phase epitaxy on hexagonally patterned sapphire substrates. Non-c-planar growth is found inside the etched honeycombs which in part hinders coalescence of the c-plane AlGaN layer growing on top of the ridges. From X-ray diffraction, electron backscatter diffraction and scanning electron microscopy, the orientations of the parasitic crystallites were identified as {11-22} and {1-103} AlGaN growing on m-plane sapphire sidewalls as well as c-plane oriented AlGaN growing on n-plane sidewall facets which are located in the corners of the combs. According to the geometry of parasitic crystallites, it is further observed, that the sernipolar growth occurring on sapphire m-plane sidevvalls does not hinder the coalescence of c-plane AlGaN growing on Lop of the ridges, whereas fast propagation of parasitic crystallites nucleating on n-plane sidewall facets leads to delayed layer coalescence. (C) 2014 Elsevier B.V. All rights reserved.