화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.39, No.25, 13174-13179, 2014
Synthesis of novel hollow microflowers (NHMF) of Nb3O7F, their optical and hydrogen storage properties
A two step, facile surfactant free hydrothermal route was adopted to synthesize Nb3O7F novel hollow microflowers (NHMF). Time dependent experiments were performed which suggested Nb3O7F-NHMF were formed due to Ostwald-ripening process. Raman spectroscopy was conducted to understand different vibrational modes of Nb3O7F-NHMF. Its characteristic band at 692 cm(-1) was observed which is associated to NbO6 octahedron sharing. The bandgap of 3.2 eV was calculated by using UV-VIS-NIR absorption spectrum. Considering importance of layered structures in energy storage applications, hydrogen storage ability of Nb3O7F-NHMF were measured for the first time. The maximum values of hydrogen absorption for Nb3O7F-NHMF at 373 K and 473 K were 0.789 wt.% and 1.08 wt.%, respectively. The hydrogen storage measurements revealed the potential of Nb3O7F-NHMF as prospective material for energy storage applications. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.