화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.128, 27-35, 2014
Influence of copper concentration in solutions on the growth mechanism and performance of electrodeposited Cu(In,Al)Se-2 solar cells
We conducted a chronoamperometric study to observe the electrochemical behaviors of the nucleation mechanism of electrodeposited Cu(In,Al)Se-2 films. A change from instantaneous nucleation to progressive nucleation was observed by increasing the copper concentration. SEM and EDS analyses demonstrated that the surface morphologies and chemical compositions of precursor and post-annealed Cu(In, Al)Se-2 films were influenced by the nucleation mechanism. They exhibited that Cu(In,Al)Se-2 films had roughly cauliflower-like and triangular structures with Cu-poor composition at the instantaneous nucleation mechanism, whereas smooth and round structures with Cu-rich composition at the progressive nucleation mechanism. Additionally, the quality, growth orientation, composition phase, and optical energy band gap of Cu(In,Al)Se-2 films were examined using X-ray diffraction (XRD) patterns, Raman spectra, and (alpha hv)(2) vs. hv plots (UV-vis). Thereafter, the performances of rudimentary Cu(In,Al) Se-2 solar cells fabricated at various copper concentrations were discussed, the conversion efficiency of electrodeposited Cu(In,Al)Se-2 solar cells were unpublished in previous literatures. Our studies demonstrated that the performances of Cu(In,Al)Se-2 solar cells were significantly related to the surface morphology and composition of Cu(In,Al)Se-2 absorber layer. The highest conversion efficiency of Cu(In, Al)Se-2 solar cells fabricated at a 2-mM copper concentration was 1.96% with open-circuit voltage, short-circuit current, fill factor, R-sh and R-s values of 0.189 V, 29.21 mA/cm(2), 35.4%, 125 Omega and 2.82 Omega, respectively. (C) 2014 Elsevier B.V. All rights reserved.