화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.3, No.4, 282-287, December, 1997
Syntheses and Physical Properties of Two-Component Polyurethane Coatings Using Bromine-Containing Aromatic Modified Polyesters
Bromine-containing aromatic modified polyester polyols were synthesized by two-step condensation reactions. Intermediate was synthesized by the esterification of m-bromobenzoic acid with trimethylolpropane in the first step. Polycondensation of the intermediate, 1,4-butanediol, and trimethylolpropane with adipic acid was carried out. Two-component polyurethane coatings were prepared by blending these modified polyester polyols and polyisocyanate. Physical properties of these new coatings were found comparable to non-bromine containing coatings, showing rapid drying character and 18 hours of pot-life. The modified coatings with 30wt% m-bromobenzoic acid also showed a self-extinguishing property
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