The effect of GaAs (1 0 0) substrate misorientation on metamorphic high electron mobility transistor nanoheterostructure In0.64Al0.3As/In0.7Ga0.3As properties was studied by the means of Hall measurements, photoluminescence spectroscopy, X-ray diffraction, TEM and STEM measurements. The identical heterostructures with step-graded metamorphic buffer InAlAs were grown by MBE on (1 0 0) GaAs substrates exactly oriented and 2 degrees misoriented towards [0 - 1 - 1] direction and the detailed comparison of electronic and structural properties was performed. The increase of electron density by 40% was found in the heterostructure grown on misoriented GaAs substrate though Si doping concentration in delta-layers was the same for both samples. In addition the substrate misorientation affected some of the heterostructure structural properties: the QW heterointerfaces were found to be more broadened, the residual strain in the In0.64Al0.36As barrier region was higher and the surface morphology was rougher in the heterostructure on (1 0 0)+2 degrees substrate as compared to that on the (1 0 0) GaAs substrate. (c) 2014 Elsevier By. All rights reserved.