화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.47, 437-440, 2012
Thermodynamic interrelation between excess limiting partial molar characteristics of a liquid nonelectrolyte
On the basis of thermodynamic analysis, it is concluded that the excess limiting partial molar volume, like the excess limiting partial molar enthalpy, can be considered as a solvation-related characteristic of a liquid nonelectrolyte. A thermodynamically grounded interrelation between standard volumetric and enthalpic effects of solution of a liquid nonelectrolyte (or series of nonelectrolytes) is suggested. (C) 2011 Elsevier Ltd. All rights reserved.