화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.38, No.29, 13091-13096, 2013
Synthesis of CdS/CNTs photocatalysts and study of hydrogen production by photocatalytic water splitting
A series of CdS and CdS/CNTs photocatalysts were successfully prepared by hydrothermal method and they were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), UV-visible optical absorption spectra (UV-Vis), etc. By studying their photocatalytic properties, it is found that, for CdS, photocatalysts prepared in appropriate alkaline environment presented higher hydrogen production activity, reaching 794.6 mu mol h(-1) g(-1); the photocatalytic activity of CdS was obviously enhanced by combining it with CNTs via a special two-step hydrothermal method, and the corresponding hydrogen production rate reached 1.771 mmol h(-1) g(-1); the photocatalytic activity was further improved by loading co-catalyst NiS, achieving 12.13 mmol h(-1) g(-1). Crown Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.