화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.37, No.23, 18133-18139, 2012
Enhancement of hydrogen-storage performance of MgH2 by Mg2Ni formation and hydride-forming Ti addition
MgH2, rather than Mg, was used as a starting material in this work. A sample with a composition of MgH2-10Ni-4Ti was prepared by reactive mechanical grinding. Activation of the sample was completed after the first hydriding cycle. At n = 1, the sample desorbed 2.53 wt% H for 10 min, 3.99 wt% H for 20 min, 4.58 wt% H for 30 min, and 4.68 wt% H for 60 min at 593 K under 1.0 bar H-2. At n = 2, the sample absorbed 3.59 wt% H for 5 min, 4.55 wt% H for 25 min, and 4.60 wt% H for 45 min at 593 K under 12 bar H-2. The inverse dependence of the hydriding rate on the temperature in the initial stage and the normal dependence of the hydriding rate on the temperature in the later stage were discussed. The rate-controlling step for the dehydriding reaction of activated MgH2-10Ni-4Ti was analyzed as the chemical reaction at the hydride/alpha-solid solution interface. Copyright (c) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.