화학공학소재연구정보센터
Fuel, Vol.123, 66-72, 2014
The effect of post-processing conditions on aminosilane functionalizaiton of mesocellular silica foam for post-combustion CO2 capture
The objective of this research is to develop amine-grafted mesocellular silica foams (MCFs) based CO2 sorbents. The template of the as-synthesized MCFs was removed by calcination or ethanol extraction method. The obtained template-free MCFs were grafted with 3-aminopropyltriethoxysilane (APS) or 3-(2-aminoethylamino)-propyl-dimethoxymethylsilane (APMS). These new composite sorbents were characterized by nitrogen adsorption/desorption, Fourier transform infrared spectroscopy (FTIR), and thermal gravimetric analysis (TGA). The infrared results indicate that more silanol groups were preserved on solvent-extracted MCF than that on calcined MCF. CO2 capture performances of the sorbents were evaluated using a fixed-bed reactor equipped with an online mass spectrometer (MS). Experimental results show that the solvent-extracted MCF grafted with APMS exhibited a higher CO2 adsorption capacity (1.54 mmol/g) under the condition of 10.0% (v/v) CO2 in N-2 at 60 degrees C. It was also found that the APMS-grafted sorbents are more capable in CO2 sorption than APS-grafted ones possibly due to the higher amine content of the formers, and the CO2 uptake can be further enhanced to 2.02 mmol/g in the presence of moisture. Cyclic CO2 adsorption-desorption test results indicate that the composite sorbents are stable and regenerable. (C) 2014 Elsevier Ltd. All rights reserved.