화학공학소재연구정보센터
Chemical Engineering Science, Vol.73, 79-85, 2012
Surfactant effects on hydrate formation in an unstirred gas/liquid system: An experimental study using methane and micelle-forming surfactants
This paper reports an experimental study in which we intended to obtain a better understanding of the possible role of surfactant micelles on the formation of a clathrate hydrate in a quiescent methane/liquid-water system. The experiments were performed using a laboratory-scale, isobaric hydrate-forming reactor, which was initially composed of a 300-cm(3) aqueous phase and a similar to 640-cm(3) methane-gas phase, then successively provided with methane such that the system pressure was held constant at 3.9 or 4.0 MPa. The surfactants used in this study were lithium dodecyl sulfate (LDS), dodecylbenzene sulfonic acid (DBSA), and sodium oleate (SO), which have sufficiently low Krafft points and hence, unlike sodium alkyl sulfates (sodium dodecyl sulfate and its homologues), allow the micelle formation under such typical hydrate-forming conditions as those used in this study (similar to 275 K in temperature and 3.9 4.0 MPa in pressure). Significant increases in the rate of hydrate formation and the final water-to-hydrate conversion ratio were simultaneously observed by the addition of LDS to the aqueous phase up to concentrations in the range from similar to 0.6 to similar to 1.6 times the relevant critical micelle concentration (CMC). Neither the rate of hydrate formation nor the final water-to-hydrate conversion ratio exhibited any appreciable change in the above concentration range. Similar observations were obtained by the addition of DBSA to the aqueous phase up to the concentrations that ranged from similar to 0.5 to similar to 2.9 times the relevant CMC. Based on these observations, we have concluded that micelles of LDS and DBSA have no practical effect on hydrate formation. No substantial promotion of hydrate formation was detected by the addition of SO to the aqueous phase up to concentrations that ranged from similar to 0.8 to similar to 4.2 times the relevant CMC. (C) 2012 Elsevier Ltd. All rights reserved.