화학공학소재연구정보센터
Applied Surface Science, Vol.290, 66-70, 2014
Rear passivation of commercial multi-crystalline PERC solar cell by PECVD Al2O3
Low-cost high-efficiency solar cells are the key to achieve grid parity with photovoltaic devices. Multicrystalline silicon (mc-Si) solar cells are low-cost but low-efficiency. High-quality rear passivation is essential for the achievement of this goal. This dielectric stack, in conjunction with a local back surface field, produced mc-Si passivated emitter and rear cell (PERC) which efficiency exceeded 18.6%. The peak efficiency of 18.63% was achieved with J(sc) of 37.44 mA/cm(2) and V-oc of 638 mV on commercial grade mc-Si wafers. Detailed characterization and modeling revealed that the increase in V-oc and J(sc) is the result of increased back surface reflectance from 74.8% to 90.7% and reduced back surface recombination velocity from 1800 to 260 cm/s. It was observed that the efficiency of mc-Si PERC solar cells decreased in degradation experiment. (C) 2013 Elsevier B.V. All rights reserved.