화학공학소재연구정보센터
Applied Surface Science, Vol.285, 885-892, 2013
Polyethylene naphthalate as an excellent candidate for ripple nanopatterning
The surface of polyethylene naphthalate (PEN) foils was exposed to KrF excimer laser treatment. Due to presence of condensed benzene rings has this polymer better mechanical, chemical and thermal properties in comparison to polyethylene terephthalate, which is widely applicable in electronic devices and also as tissue cell carriers. The influence of laser fluence and number of laser pulses on surface chemistry and morphology was determined. The surface morphology was studied with atomic force microscopy (AFM) in combination with scanning electron microscopy and focused ion beam (FIB-SEM). Surface wettability was characterized by the contact angle measurement. Surface chemistry was evaluated from XPS spectra. The optimal PEN process parameters with the most regular pattern were determined. The foils with optimal ripple pattern were consequently sputtered with gold nanolayers of 100 nm thickness. The parameters of ripple pattern after the metallization were introduced. It was found that the gold nanolayer is formed of electrically continuous wires, the ripple pattern was maintained. (C) 2013 Elsevier B.V. All rights reserved.