화학공학소재연구정보센터
Polymer, Vol.54, No.25, 6860-6866, 2013
Stress induced lamellar thickening in poly(ethylene succinate)
The crystalline structure evolution of poly(ethylene succinate) during tensile deformation was investigated by in-situ synchrotron X-ray scattering. Crystal phase transition from alpha to beta form was confirmed to be fully reversible upon stress loading and unloading. An increase of long period was observed during the alpha-beta crystal transition, which was attributed to the increase of both amorphous layer thickness and crystalline layer thickness (lamellar thickness). The crystalline layer thickness was scaled with the fraction of beta crystal, and the change of which was in well agreement with the difference in the repeating length along the crystallographic c axis. Both the crystalline layer thickness and the amorphous layer thickness were fully recoverable. A possible molecular model was proposed to visualize the mechanism for the crystal transition and lamellar thickening. (C) 2013 Elsevier Ltd. All rights reserved.