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Journal of the Korean Industrial and Engineering Chemistry, Vol.6, No.4, 747-749, August, 1995
ㅠ-Allyl 및 Diethylcarbamate기에 의해 다리결합된 이핵팔라듐착물의 합성 및 확인
Synthesis and Characterization of Dinuclear Palladium Complex Bridged by π-Allyl- and Diethylcarbamate Group
초록
1atm의 이산화탄소 분위기 하에서 diethylamine과 Pd(η3-allyl)Me(PPh3)의 반응에 의해서 63%의 수율로 이핵팔라듐착물인 (PPh3)Pd(μ-η3-C3H5)(μ-O2CNEt,2)이 얻어졌으며, IR, NMR, 원소분석에 의해 구조를 화인했다. 또, 메탄올과 반응하여 allylether(CH2=CHCH2OMe)가 18%의 수율로 얻어졌다.
Reaction of Pd(η3allyl)Me(PPh3) with diethylamine under an atmosphere of carbon dioxide gave a dinuclear palladium complex (PPh3)Pd(μ-η3-C3H5)(μ-O2CNEt2) in 63% yield which was characterized by IR, NMR, and elemental analysis. Similar reaction with methanol gave an allylether CH2=CHCH2OMe of 18% yield.
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