화학공학소재연구정보센터
Inorganic Chemistry, Vol.52, No.8, 4124-4126, 2013
Zn7O2(RCOO)(10) Clusters and Nitro Aromatic Linkers in a Porous Metal-Organic Framework
A new metal-organic framework, CALF-22 comprising Zn7O2(COO)(10) secondary building units and 2-nitro-1,4-benzenedicarboxylate, is reported. The porosity and gas adsorption of N-2, H-2, CO2, and CH4 are studied, and CALF-22 has a surface area in excess of 1000 m(2)/g. The stability of the larger zinc cluster and the effect of the nitro group on gas sorption are also studied.