화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.3, No.1, 64-71, March, 1992
아민을 리간드로 갖는 산소가교 팔라듐 착화합물의 합성에 관한 연구
The Study of Preparation of Dioxygen Bridged Palladium Complexes Having Amine Ligands
초록
초과산화이온(O2-)의 발생원으로서 KO2를 사용하여 새로운 형태의 산소가교 팔라듐 착화합물을 합성했다. 이 방법은 구핵치환반응과 전자이동에 의한 반응으로서 원자가가 낮은 전이금속 착화합물에 산소분자를 산화적으로 부가시켜 합성한 종전의 방법과는 완전히 다르다. 초과산화이온(O2-)에 의하여 아민을 리간드로 갖는 새로운 형태의 3종류의 산소가교 팔라듐 착화합물을 합성했다.
New type dioxygen bridged complexes of palladium were prepared by using KO 2 as a source of superoxide ion(O2-). The method is completely different from the traditional one which has adopted the oxidative addition of molecular oxygen to prepare the dioxygen complexes. This reaction proceeds via nucleophilic displacement followed by electron transfer reaction. Three new type dioxygen complexes of palladium having amine ligands were prepared and characterized by the application of the reaction of O2-.
  1. Vaska L, Accounts Chem. Res., 9, 175 (1976) 
  2. Henrici-Olive G, Olive S, Angew. Chem.-Int. Edit., 13, 29 (1974) 
  3. Mague JT, Wilkinson G, J. Chem. Soc., 1736 (1966)
  4. Laing KR, Ropper WR, Chem. Commun., 1556 (1968)
  5. Graham BW, Laing KR, Connor CJO, Ropper WR, Chem. Commun., 1272 (1970)
  6. Carit BE, Grundy KR, Ropper WR, Chem. Commun., 127 (1971)
  7. Wilke G, Schatt H, Heimbach P, Angew. Chem.-Int. Edit., 79, 62 (1967)
  8. Otsuka S, Nakamura A, J. Am. Chem. Soc., 91, 6994 (1969) 
  9. Otsuka S, Nakamura A, Inorg. Chem., 11, 2058 (1972) 
  10. Chatt J, Duncanson LA, J. Chem. Soc., 2939 (1953) 
  11. Dewar MJS, Bull. Soc. Chim. Fr., 18c, 79 (1951)
  12. Laplace SJ, Ibers JA, J. Am. Chem. Soc., 87, 2581 (1965) 
  13. McGinnety JA, Payne NC, Ibers JA, J. Am. Chem. Soc., 91, 6031 (1969) 
  14. Mimoun H, deRoch IS, Sajus L, Tetrahedron, 26, 37 (1970)
  15. Bennett MJ, Donaldson PB, J. Am. Chem. Soc., 93, 3307 (1971) 
  16. Suzuki H, Mizutani K, Moro-Oka Y, Ikawa T, J. Am. Chem. Soc., 101, 748 (1979) 
  17. Chung PJ, Suzuki H, Moro-Oka Y, Ikawa T, Chem. Lett., 63 (1980) 
  18. 정평진, 대한화학회지, 28, 135 (1984)
  19. 정평진, 대한화학회지, 30, 516 (1986)
  20. Calligaris M, Nardin G, Randaccio L, Ripamonti A, J. Chem. Soc., 1069 (1970)
  21. Matsushita T, Yarino T, Masuda I, Shono T, Shinra K, Bull. Chem. Soc. Jpn., 46, 1712 (1973) 
  22. Cope AC, Kliegman JM, Friedrich EC, J. Am. Chem. Soc., 89, 287 (1967) 
  23. Cope AC, Friedrich EC, J. Am. Chem. Soc., 90, 909 (1968) 
  24. San Fillippo J, Chern CI, Valentine JS, J. Org. Chem., 40, 1678 (1975) 
  25. Johnson RA, Nidy EG, J. Org. Chem., 40, 1681 (1975) 
  26. Corey EJ, Nicolaou KC, Shibasaki M, Machida Y, Shiner CS, Tetrahedron Lett., 3183 (1975) 
  27. Corey EJ, Nicolaou KC, Shibasaki M, Machida Y, Shiner CS, Chem. Commun., 658 (1975)
  28. Poupko R, Rosenthal I, J. Phys. Chem., 77, 1722 (1973)