화학공학소재연구정보센터
Thin Solid Films, Vol.516, No.14, 4574-4577, 2008
Durability of doped zinc oxide/silver/doped zinc oxide low emissivity coatings in humid environment
The relationship between internal stress of doped zinc oxide films and durability of doped zinc oxide/silver/doped zinc oxide low emissivity (low-e) coatings in humid environment was investigated. Aluminum, titanium, tin, chromium, silicon, gallium, magnesium, boron, barium, and calcium were chosen as a doping element in sputtering targets. Ratios of dopant/zinc in the oxide targets were 4/96-5/95 at.%. Films were formed by radio frequency sputtering. Doping of barium and calcium to the zinc oxide film led to a large increase in the internal stress. Doping of the other elements resulted in decreasing the internal stress. It was concluded that durability of the low-c coatings in humid environment closely correlated with the internal stress of the oxide layers. (C) 2007 Elsevier B.V. All rights reserved.