화학공학소재연구정보센터
Materials Research Bulletin, Vol.45, No.8, 910-915, 2010
Growth, spectroscopic properties and laser performance of Nd3+-doped potassium ytterbium tungstate laser crystal
The 5 at.% Nd3+-doped potassium ytterbium tungstate (Nd3+:KYb(WO4)(2), hereafter Nd:KYbW) laser crystal with the dimension up to 28 mm x 15 mm x 12 mm was grown by the top seeded solution growth (TSSG) method. The infrared spectrum of crystal sample was measured, and the vibrational peaks were assigned. According to the absorption and emission spectra of crystal sample, the absorption and emission cross-sections are 16.03 x 10(-2) cm(2) at 808 nm and 10.72 x 10(-20) cm(2) at 1067 nm, respectively. The fluorescence life of F-4(3/2) energy level is 196.33 mu s, and the fluorescence branching ratio for the F-4(3/2)-I-4(11/2) transition at 1067 nm is 55.74%. The energy transfer between Nd3+ and Yb3+ ions was observed from the fluorescence spectra pumped by 808 and 980 nm LD sources and the Stark levels of Yb3+ in Nd:KYbW crystal were determined. Highly efficient laser output up to 305 mW of Nd:KYbW crystal at 1067 nm has been achieved under pumping by a CW 808 nm laser diode at room temperature. The optical-optical conversion efficiency is 33.9% and the slope efficiency is 46.8%. (C) 2010 Elsevier Ltd. All rights reserved.