화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.55, No.1, 205-210, 2010
Densities, Viscosities, Refractive Indices, and Heat Capacities of Poly(ethylene glycol-ran-propylene glycol) plus Esters of Carbonic Acid at (293.15 and 313.15) K and at Atmospheric Pressure
Densities, rho, dynamic viscosities, eta, refractive indices. n(D), and heat capacities, C(rho), for the binary mixtures containing poly(ethylene glycol-ran-polypropylene glycol) + esters of carbonic acid were determined at (293.15 and 313.15) K and at atmospheric pressure using an Anton Paar density meter, it Schott-Gerate AVS viscometer, an Abbe refractometer, and a Perkin-Elmer differential scanning calorimeter. Volume variations, Delta V, during mixing and deviations of the dynamic viscosities, Delta eta, were obtained at these temperatures and are negative for all mixtures. Experimental data were fitted to the Redlich-Kister equation, and the adjustable parameters and the standard deviations between experimental and calculated values were estimated.