Quantitative determination of surface carboxyl groups in vinyl acid modified styrene/butadiene copolymer latexes: I. Latexes prepared with acrylic acid
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2016, International Journal of Adhesion and AdhesivesAttributes of the latex emulsion processing and its role in morphology and performance in paints
2011, Progress in Organic CoatingsCitation Excerpt :However, properties of carboxylated lattices are greatly influenced by the method of insertion, nature of the carboxylic monomer and also the distribution of carboxylic acid group in serum, surface or buried in the latex. It has also been observed that the rate of polymerization of bifunctional carboxylic acids such as fumaric [19], maleic acid and more specifically itaconic acid (IA) [1–9] is slower than that of acrylate esters and therefore their presence is likely to reduce the rate of propagation in the aqueous phase. The incorporation of even small amounts of IA into the copolymer significantly increases the solubility and hence the polarity of the emulsion.
Surface characterization of functionalized latexes with different surface functionalities using rheometry and dynamic light scattering
2010, Journal of Colloid and Interface ScienceEffects of carboxylic monomers on the styrene miniemulsion polymerizations stabilized by SDS/alkyl methacrylates
2001, PolymerCitation Excerpt :This is probably due to the fact that the probability for the oligomeric radicals comprising ST and MAA to participate the particle formation process in the aqueous phase is increased as compared to the AA counterpart. Another contributing factor is that the comonomer MAA can be distributed more uniformly in the latex particles in comparison with AA [30–32]. This will then alleviate the effect of the retarded entry of radicals into the carboxylated latex particles shown in Fig. 3b.