Radiochemical study of the radical copolymerization of styrene and methyl methacrylate
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Does bimolecular termination dominate in benzoyl peroxide initiated styrene free-radical polymerization?
2020, PolymerCitation Excerpt :Based on the number of the initiator fragment in every polymer chain, it is concluded that most chains terminate dominantly or entirely through bimolecular coupling termination in free-radical polymerization [1–4,16–22], small aliphatic radical experiments supported the bimolecular termination mode [23–26]. It is also considered that chains almost exclusively terminate by coupling termination in the free-radical polymerization of styrene, methyl acrylate, and acrylonitrile, but a combination of coupling and disproportionation terminations occurs in the free-radical polymerization of methyl methacrylate and vinyl acetate [27–30]. Recently, several studies were reported on the chain radical termination mechanism [31–41], structurally well-defined polymer end radicals were used in those studies, the selectivity of bimolecular coupling termiantion and disproportionation was focused on.
A Critical Assessment of the Kinetics and Mechanism of Initiation of Radical Polymerization with Commercially Available Dialkyldiazene Initiators
2019, Progress in Polymer ScienceCitation Excerpt :A comparison with the rate of initiator decomposition then provides fi. With respect to dialkyldiazenes, the technique has been applied to AIBN [96,140,142–144], ACHN [145] and 2-cyano-2-propylformamide [146]. The method is now seldom used.
The rate of copolymerization of styrene and methylmethacrylate-I. Low conversion kinetics
1989, European Polymer JournalA highly transparent and thermally stable copolymer of 1-adamantyl methacrylate and styrene
2015, Polymer International
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