Regular ArticleRelationship between the Zirconia-Promoted Reduction in the Rh-Loaded Ce0.5Zr0.5O2Mixed Oxide and the Zr–O Local Structure
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Effects of thermal treatment conditions on redox properties of ceria-zirconia materials
2023, Journal of Rare EarthsOn the Co solubility in Ce<inf>0.9</inf>Zr<inf>0.1</inf>O<inf>2</inf> nanoparticles studied by EXAFS
2022, Journal of Solid State ChemistryInvestigation of reactive perovskite materials for solar fuel production via two-step redox cycles: Thermochemical activity, thermodynamic properties and reduction kinetics
2022, Materials Chemistry and PhysicsCitation Excerpt :Doping with Zr has a beneficial impact on ceria reduction extent: the reduction yield increases from 55 μmol/g for pure ceria to 176 μmol/g for CeZr37. The lattice distortion induced by the incorporation of Zr4+ enhances oxygen mobility, explaining the higher O2 yield obtained with Zr-doped ceria [60,61]. The total amount of dopant in CeZr27Al10 and CeZr37 is similar (37%), however the O2 released by CeZr27Al10 (129 μmol/g) is significantly lower than the value measured for CeZr37 (176 μmol/g).
Structure, synthesis, and catalytic properties of nanosize cerium-zirconium-based solid solutions in environmental catalysis
2019, Chinese Journal of CatalysisCitation Excerpt :Unfortunately, these conventional techniques fail in the investigation of the low crystallization degree materials, however, which are very important in heterogeneous catalysis. More advanced techniques, such as neutron diffraction and EXAFS, have proved to be effectively on determining inhomogeneity and detecting complementary structural information [36,62–65]. Moreover, Montini et al. [66] investigated the potential of luminescence spectroscopy for identifying the homogeneity of CZO materials using Eu(III) ion as a structural probe.
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