Thermal degradation kinetics of polybutadiene rubber
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Degradation and stability studies of butadiene rubber: Correlation between experimental and computational values
2023, Materials Today CommunicationsPorous silicon covalently-grafted with chloro-styrenic carbons for fast Li<sup>+</sup> diffusion and durable lithium-storage capability
2023, Journal of Power SourcesCitation Excerpt :To address these issues, one-pot thermolytic grafting of styrene polymers (polystyrene (PS) and poly(4-chlorostyrene) (PCS)) is reported for the facile synthesis of porous Si (pSi) particles covalently sheathed with a thin styrenic carbon layer. PS and PS-derivatives are commercially available polymers that are depolymerized at ∼400 °C with simultaneous generation of styrenic fragments, which is quite lower than that of other polymers without producing phenylic radicals for thermal grafting reaction, (i.e. polyethylene, polybutadiene, polyvinylidene fluoride, etc.) [25–27]. Furthermore, PS and PCS are soluble in numerous organic solvents that benefits the infiltration process of polymer precursors to form a thin and uniform carbon layer [28].
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2017, Journal of Molecular StructureCitation Excerpt :As early as 1960s, researchers [2] found the catalytic activity of the rare earth compounds in the stereospecific polymerization of conjugated dienes and then began the exploratory research work [3,4] of rare earth complex catalysts on the basis of this finding. Since 1971, the industrial development of rare earth polybutadiene rubber [5–7] by using rare earth complex catalysts [8,9] was carried out in the world [2]. The research of rare earth polybutadiene rubber had also made breakthrough progress in Britain, Italy, Germany, Japan and other countries [10–12].
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2015, Thermochimica ActaCitation Excerpt :Also, the water content is very low, while, especially for SBR, there are significant amounts of additives. All these results do agree well with previously published values for these types of rubbers [19,20,21,24,28]. Kinetic modelling of devolatilisation is generally based on the conversion (α), which is defined as,