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Photocatalytic performance of Z-scheme SrCO3-SrTiO3/Ag3PO4 heterojunction for tetracycline hydrochloride degradation

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Abstract

Visible-light-driven photocatalysis, as an emerging environmental restoration technology, has become a focus of attention recently. In this work, a novel SrCO3-SrTiO3/Ag3PO4 heterojunction was successfully synthesized, and its structure, composition, and optical performance were systematically characterized. In addition, SrTiO3/Ag3PO4 was also synthesized, and its type II heterojunction had certain defects. The active species trapping experiments of SrCO3–SrTiO3/Ag3PO4 showed that ·OH and ·O2 participated during the reaction. The photodegradation efficiency of SrCO3–SrTiO3/Ag3PO4 heterojunction was 1.4 times and 2.0 times that of Ag3PO4 and SrCO3–SrTiO3, respectively. A novel Z-scheme mechanism could be used to explain the photoreaction process of SrCO3–SrTiO3/Ag3PO4. The excellent photocatalytic property was due to the enhancement of visible-light absorption, the effective separation of photogenerated charges, and the generation of abundant active species.

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References

  1. Sasaki Y, Iwase A, Kato H, Kudo A (2008) The effect of co-catalyst for Z-scheme photocatalysis systems with an Fe3+/Fe2+ electron mediator on overall water splitting under visible light irradiation. J Catal 259(1):133–137

    CAS  Google Scholar 

  2. Chen Y, Liang W, Li Y, Wu Y, Chen Y, Xiao W, Zhao L, Zhang J, Li H (2019) Modification, application and reaction mechanisms of nano-sized iron sulfide particles for pollutant removal from soil and water: A review. Chem Eng J 362:144–159

    CAS  Google Scholar 

  3. Chen Y, Liu Y, Li Y, Wu Y, Chen Y, Liu Y, Zhang J, Xu F, Li M, Li L (2020) Synthesis, application and mechanisms of Ferro-Manganese binary oxide in water remediation: A review. Chem Eng J 388:124313

    CAS  Google Scholar 

  4. Chen Y, Xu R, Li Y, Liu Y, Wu Y, Chen Y, Zhang J, Chen S, Yin H, Zeng Z, Wang S, Peng Z (2020) La(OH)3-modified magnetic CoFe2O4 nanocomposites: A novel adsorbent with highly efficient activity and reusability for phosphate removal. Colloid Surface A 599:124870

    CAS  Google Scholar 

  5. Chen X, Shen S, Guo L, Mao SS (2010) Semiconductor-based photocatalytic hydrogen generation. Chem Rev 110(11):6503–6570

    CAS  Google Scholar 

  6. Zhang C, Yu K, Feng Y, Chang Y, Yang T, Xuan Y, Lei D, Lou L, Liu S (2017) Novel 3DOM-SrTiO3/Ag/Ag3PO4 ternary Z-scheme photocatalysts with remarkably improved activity and durability for contaminant degradation. Appl Catal B: Environ 210:77–87

    CAS  Google Scholar 

  7. Ouyang S, Li P, Xu H, Tong H, Liu L, Ye J (2014) Bifunctional-nanotemplate assisted synthesis of nanoporous SrTiO3 photocatalysts toward efficient degradation of organic pollutant. ACS Appl Mater Interfaces 6(24):22726–22732

    CAS  Google Scholar 

  8. Nosaka Y, Takahashi S, Mitani Y, Qiu X, Miyauchi M (2012) Reaction mechanism of visible-light responsive Cu(II)-grafted Mo-doped SrTiO3 photocatalyst studied by means of ESR spectroscopy and chemiluminescence photometry. Appl Catal B: Environ 111–112:636–640

    Google Scholar 

  9. Luo X, He G, Fang Y, Xu Y (2018) Nickel sulfide/graphitic carbon nitride/strontium titanate (NiS/g-C3N4/SrTiO3) composites with significantly enhanced photocatalytic hydrogen production activity. J Colloid Interf Sci 518:184–191

    CAS  Google Scholar 

  10. Jin S, Dong G, Luo J, Ma F, Wang C (2018) Improved photocatalytic NO removal activity of SrTiO3 by using SrCO3 as a new co-catalyst. Appl Catal B: Environ 227:24–34

    CAS  Google Scholar 

  11. Turekian KK, Wedepohl KH (1961) Distribution of the Elements in Some Major Units of the Earth’s Crust. Geol Soc Am Bull 72(2):175–191

    CAS  Google Scholar 

  12. Divya A, Mathavan T, Harish S, Archana J, Benial AMF, Hayakawa Y, Navaneethan M (2019) Synthesis and characterization of branchlet-like SrCO3 nanorods using triethylamine as a capping agent by wet chemical method. Appl Surf Sci 487:1271–1278

    CAS  Google Scholar 

  13. Song L, Zhang S, Chen B (2009) A novel visible-light-sensitive strontium carbonate photocatalyst with high photocatalytic activity. Catal Commun 10(12):1565–1568

    CAS  Google Scholar 

  14. Fu J, Kyzas GZ, Cai Z, Deliyanni EA, Liu W, Zhao D (2018) Photocatalytic degradation of phenanthrene by graphite oxide-TiO2-Sr(OH)2/SrCO3 nanocomposite under solar irradiation: Effects of water quality parameters and predictive modeling. Chem Eng J 335:290–300

    CAS  Google Scholar 

  15. Raschetti M, Byzynski G, Ribeiro C, Longo E (2017) N-doping SrTiO3@SrCO3 heterostructure electrode: Synthesis, electrochemical characterization, and varistor application. Ceram Int 43(15):11722–11732

    CAS  Google Scholar 

  16. Pan X, Chen X, Yi Z (2016) Photocatalytic oxidation of methane over SrCO3 decorated SrTiO3 nanocatalysts via a synergistic effect. Phys Chem Chem Phys 18(46):31400–31409

    CAS  Google Scholar 

  17. Yue X, Zhang J, Yan F, Wang X, Huang F (2014) A situ hydrothermal synthesis of SrTiO3/TiO2 heterostructure nanosheets with exposed (001) facets for enhancing photocatalytic degradation activity. Appl Surf Sci 319:68–74

    CAS  Google Scholar 

  18. Chen X, Tan P, Zhou B, Dong H, Pan J, Xiong X (2015) A green and facile strategy for preparation of novel and stable Cr-doped SrTiO3/g-C3N4 hybrid nanocomposites with enhanced visible light photocatalytic activity. J Alloys Compd 647:456–462

    CAS  Google Scholar 

  19. Chang Y, Yu K, Zhang C, Yang Z, Feng Y, Hao H, Jiang Y, Lou L, Zhou W, Liu S (2017) Ternary CdS/Au/3DOM-SrTiO3 composites with synergistic enhancement for hydrogen production from visible-light photocatalytic water splitting. Appl Catal B: Environ 215:74–84

    CAS  Google Scholar 

  20. Zhang Q, Huang Y, Peng S, Zhang Y, Shen Z, Cao J, Ho W, Lee SC, Pui DYH (2017) Perovskite LaFeO3 -SrTiO3 composite for synergistically enhanced NO removal under visible light excitation. Appl Catal B: Environ 204:346–357

    CAS  Google Scholar 

  21. Guo J, Ouyang S, Li P, Zhang Y, Kako T, Ye J (2013) A new heterojunction Ag3PO4/Cr-SrTiO3 photocatalyst towards efficient elimination of gaseous organic pollutants under visible light irradiation. Appl Catal B: Environ 134:286–292

    Google Scholar 

  22. Guan X, Guo L (2014) Cocatalytic Effect of SrTiO3 on Ag3PO4 toward Enhanced Photocatalytic Water Oxidation. ACS Catal 4(9):3020–3026

    CAS  Google Scholar 

  23. Cai T, Liu Y, Wang L, Zhang S, Zeng Y, Yuan J, Ma J, Dong W, Liu C, Luo S (2017) Silver phosphate-based Z-Scheme photocatalytic system with superior sunlight photocatalytic activities and anti-photocorrosion performance. Appl Catal B: Environ 208:1–13

    CAS  Google Scholar 

  24. Zhang W, Hu C, Zhai W, Wang Z, Sun Y, Chi F, Ran S, Liu X, Lv Y (2016) Novel Ag3PO4/CeO2 p-n Hierarchical Heterojunction with Enhanced Photocatalytic Performance. Materials Research 19(3):673–679

    CAS  Google Scholar 

  25. Zhang W, Hu C, Tan J, Fan Z, Chi F, Sun Y, Ran S, Liu X, Lv Y (2016) Novel α-FeOOH Nanorods/Ag3PO4 Semiconductor Composites with Enhanced Photocatalytic Activity and Stability. NANO 11(06):1650071

    CAS  Google Scholar 

  26. Jiang J, Jia Y, Wang Y, Chong R, Xu L, Liu X (2019) Insight into efficient photocatalytic elimination of tetracycline over SrTiO3 (La, Cr) under visible-light irradiation: The relationship of doping and performance. Appl Surf Sci 486:93–101

    CAS  Google Scholar 

  27. Kumar A, Rana A, Sharma G, Naushad M, A.a.H. A, C. Guo, A. I. J, F.J. Stadler, (2018) High-performance photocatalytic hydrogen production and degradation of levofloxacin by wide spectrum-responsive Ag/Fe3O4 bridged SrTiO3/g-C3N4 plasmonic nanojunctions: joint effect of Ag and Fe3O4. ACS Appl. Mater. Interfaces. 10(47):40474–40490

    CAS  Google Scholar 

  28. Liu X, Wang Z, Wu Y, Liang Z, Guo Y, Xue Y, Tian J, Cui H (2019) Integrating the Z-scheme heterojunction into a novel Ag2O@rGO@reduced TiO2 photocatalyst: Broadened light absorption and accelerated charge separation co-mediated highly efficient UV/visible/NIR light photocatalysis. J Colloid Interf Sci 538:689–698

    CAS  Google Scholar 

  29. Lin Y, Wu S, Li X, Wu X, Yang C, Zeng G, Peng Y, Zhou Q, Lu L (2018) Microstructure and performance of Z-scheme photocatalyst of silver phosphate modified by MWCNTs and Cr-doped SrTiO3 for malachite green degradation. Appl Catal B: Environ 227:557–570

    CAS  Google Scholar 

  30. Zhang Q, Huang Y, Xu L, Cao J, Ho W, Lee SC (2016) Visible-Light-Active Plasmonic Ag-SrTiO3 Nanocomposites for the Degradation of NO in Air with High Selectivity. ACS Appl Mater Interfaces 8(6):4165–4174

    CAS  Google Scholar 

  31. Chen X, Zhang W, Zhane L, Feng L, Wen J, Yang J, Zhang C, Jiang J, Wang H (2019) An urchin-like Ag3PO4/Pd/LaPO4 photocatalyst with Z-scheme heterojunction for enhanced hydrogen evolution. Appl Surf Sci 497:143771

    CAS  Google Scholar 

  32. Si Y, Li X, Yang G, Mie X, Ge L (2020) Fabrication of a novel core–shell CQDs@ZIF-8 composite with enhanced photocatalytic activity. J Mater Sci 55(27):13049–13061. https://doi.org/10.1007/s10853-020-04909-8

    CAS  Google Scholar 

  33. Zhang H, Zhao L, Wang L, Hao J, Meng X (2020) Fabrication of oxygen-vacancy-rich black-BiOBr/BiOBr heterojunction with enhanced photocatalytic activity. J Mater Sci 55(24):10785–10795. https://doi.org/10.1007/s10853-020-04700-9

    Article  CAS  Google Scholar 

  34. Chen F, Yang Q, Wang S, Yao F, Sun J, Wang Y, Zhang C, Li X, Niu C, Wang D, Zeng G (2017) Graphene oxide and carbon nitride nanosheets co-modified silver chromate nanoparticles with enhanced visible-light photoactivity and anti-photocorrosion properties towards multiple refractory pollutants degradation. Appl Catal B: Environ 209:493–505

    CAS  Google Scholar 

  35. Guo W, Zhang J, Li G, Xu C (2019) Enhanced photocatalytic activity of P-type (K, Fe) co-doped g-C3N4 synthesized in self-generated NH3 atmosphere. Appl Surf Sci 470:99–106

    CAS  Google Scholar 

  36. Xie J, Yang C, Duan M, Tang J, Wang Y, Wang H, Courtois J (2018) Amorphous NiP as cocatalyst for photocatalytic water splitting. Ceram Int 44(5):5459–5465

    CAS  Google Scholar 

  37. Han T, Chen Y, Tian G, Zhou W, Xiao Y, Li J, Fu H (2016) Hydrogenated TiO2/SrTiO3 porous microspheres with tunable band structure for solar-light photocatalytic H2 and O2 evolution. Science China Materials 59(12):1003–1016

    CAS  Google Scholar 

  38. Chen C, Li M, Jia Y, Chong R, Xu L, Liu X (2020) Surface defect-engineered silver silicate/ceria p-n heterojunctions with a flower-like structure for boosting visible light photocatalysis with mechanistic insight. J Colloid Interf Sci 564:442–453

    CAS  Google Scholar 

  39. Matsumoto Y (1996) Energy positions of oxide semiconductors and photocatalysis with iron complex oxides. J Solid State Chem 126:227–234

    CAS  Google Scholar 

  40. Wan J, Liu YN, Yin H, Huang XY, Bai MJ (2020) Synthesis and photocatalytic performance of a WSe2QD/N-GO nanocomposite under visible light irradiation. J Mater Sci 55(23):10009–10021. https://doi.org/10.1016/j.jallcom.2019.153246

    Article  CAS  Google Scholar 

  41. Guo R, Yan A, Xu J, Xu B, Li T, Liu X, Yi T, Luo S (2020) Effects of morphology on the visible-light-driven photocatalytic and bactericidal properties of BiVO4/CdS heterojunctions: A discussion on photocatalysis mechanism. J Alloys Compd 817:153246

    CAS  Google Scholar 

  42. Karpov M, Seiwert B, Mordehay V, Reemtsma T, Polubesova T, Chefetz B (2018) Transformation of oxytetracycline by redox-active Fe(III)- and Mn(IV)-containing minerals: Processes and mechanisms. Water Res 145:136–145

    CAS  Google Scholar 

  43. Zhang S, Liu Y, Gu P, Ma R, Wen T, Zhao G, Li L, Ai Y, Hu C, Wang X (2019) Enhanced photodegradation of toxic organic pollutants using dual-oxygen-doped porous g-C3N4: Mechanism exploration from both experimental and DFT studies. Appl Catal B: Environ 248:1–10

    CAS  Google Scholar 

  44. Huang K, Lv Y, Zhang W, Sun S, Yang B, Chi F, Ran S, Liu X (2015) One-step Synthesis of Ag3PO4/Ag Photocatalyst with Visible-light Photocatalytic Activity. Materials Research 18(5):939–945

    CAS  Google Scholar 

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Acknowledgement

This study was financially supported by the National Natural Science Foundation of China (51979104, and 51521006), Hunan Province Engineering &Technology Research Center for Rural Water Quality Safety (2019TP2079) and Natural Science Foundation of Hunan Province, China (2020JJ5019).

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Correspondence to Yaoning Chen or Yuanping Li.

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Chen, Y., Peng, Z., Li, Y. et al. Photocatalytic performance of Z-scheme SrCO3-SrTiO3/Ag3PO4 heterojunction for tetracycline hydrochloride degradation. J Mater Sci 56, 4356–4365 (2021). https://doi.org/10.1007/s10853-020-05529-y

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