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Preparation of activated carbon nanotube foams loaded with Ag-doped TiO2 for highly efficient photocatalytic degradation under UV and visible light

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Abstract

Titanium oxide (TiO2) has been widely investigated as a photocatalytic material for degradation of organic pollutant in waste water. However, nanosized granular TiO2 nanoparticles are hard to be recycled and re-utilized in water and many cause secondary pollution of water. Hence, we constructed a foam-like photocatalyst, which was composed of carbonaceous support: activated carbon nanotube foams and Ag-doped TiO2 nanoparticles through a method of a template synthesis and carbonization strategy. The as-prepared photocatalyst evidenced to be hierarchical macroporous and mesoporous and exhibited remarkable photocatalytic performance toward the degradation of unsymmetrical dimethylhydrazine under UV and visible light. The structure characterization and photocatalytic performance investigation confirmed that the enhanced photoresponse was attributed to the high efficiency of charge separation and the surface plasmon resonance effect of metallic Ag. The adsorption synergetic effect of the hierarchical porous structure also played an important role in photodegradation. The as-prepared photocatalyst showed great potential in the treatment of waste water containing organic pollutant.

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References

  1. Jin L, Ong WJ, Zhang R, Pickwell-MacPherson E, Yu JC (2018) Graphitic carbon nitride nanosheet wrapped mesoporous titanium dioxide for enhanced photoelectrocatalytic water splitting. Catal Today 315:103–109

    Article  Google Scholar 

  2. Gomis-Berenguer A, Velasco LF, Velo-Gala I, Ania CO (2017) Photochemistry of nanoporous carbons: perspectives in energy conversion and environmental remediation. J Colloid Interface Sci 490:879–901

    Article  CAS  Google Scholar 

  3. Komatsuda S, Asakura Y, Vequizo JJM, Yamakata A, Yin S (2018) Enhanced photocatalytic NOx decomposition of visible-light responsive F-TiO2/(N, C)-TiO2 by charge transfer between F-TiO2 and (N, C)-TiO2 through their doping levels. Appl Catal B 238:358–364

    Article  CAS  Google Scholar 

  4. Nakatani H, Hamachi R, Fukui K, Motokucho S (2018) Synthesis and activity characteristics of visible light responsive polymer photocatalyst system with a styrene block copolymer containing TiO2 gel. J Colloid Interface Sci 532:210–217

    Article  CAS  Google Scholar 

  5. Yu LF, Zhang SM, Zhang M, Chen JD (2017) Superhydrophobicity construction with dye-sensitised TiO2 on fabric surface for both oil/water separation and water bulk contaminants purification. Appl Surf Sci 425:46–55

    Article  CAS  Google Scholar 

  6. Zhang SB, Zhao YC, Yang JP, Zhang JY, Zheng CG (2018) Fe-modified MnOx/TiO2 as the SCR catalyst for simultaneous removal of NO and mercury from coal combustion flue gas. Chem Eng J 348:618–629

    Article  CAS  Google Scholar 

  7. Ji LJ, Zhang YH, Miao SY, Gong MD, Liu X (2017) In situ synthesis of carbon doped TiO2 nanotubes with an enhanced photocatalytic performance under UV and visible light. Carbon 125:544–550

    Article  CAS  Google Scholar 

  8. Ton NNT, Dao ATN, Kato K, Ikenaga T, Trinh DX, Taniike T (2018) One-pot synthesis of TiO2/graphene nanocomposites for excellent visible light photocatalysis based on chemical exfoliation method. Carbon 133:109–117

    Article  CAS  Google Scholar 

  9. An HR, Hong YC, Kim H et al (2018) Studies on mass production and highly solar light photocatalytic properties of gray hydrogenated-TiO2 sphere photocatalysts. J Hazard Mater 358:222–233

    Article  CAS  Google Scholar 

  10. Tian J, Zhao Z, Kumar A, Boughton RI, Liu H (2014) Recent progress in design, synthesis, and applications of one-dimensional TiO2 nanostructured surface heterostructures: a review. Chem Soc Rev 43:6920–6937

    Article  CAS  Google Scholar 

  11. Li C, Wang XP, Cheruvathur A, Shen YB, Xiang HW, Li YW, Niemantsverdriet JW, Su R (2018) In-situ probing photocatalytic C–C bond cleavage in ethylene glycol under ambient conditions and the effect of metal cocatalyst. J Catal 365:313–319

    Article  CAS  Google Scholar 

  12. Wu XB, Zhuang W, Lu LH et al (2017) Excellent performance of Pt-C/TiO2 for methanol oxidation: contribution of mesopores and partially coated carbon. Appl Surf Sci 426:890–896

    Article  CAS  Google Scholar 

  13. Yuan L, Weng B, Colmenares JC, Sun YG, Xu YJ (2017) Multichannel charge transfer and mechanistic insight in metal decorated 2D–2D Bi2WO6–TiO2 cascade with enhanced photocatalytic performance. Small 13:1702253

    Article  Google Scholar 

  14. Yeon Do J, Chava RK, Mandari KK et al (2018) Selective methane production from visible-light-driven photocatalytic carbon dioxide reduction using the surface plasmon resonance effect of superfine silver nanoparticles anchored on lithium titanium dioxide nanocubes (Ag@LixTiO2). Appl Catal B 237:895–910

    Article  Google Scholar 

  15. Li YF, Feng J, Dong FX et al (2017) Surface plasmon-enhanced amplified spontaneous emission from organic single crystals by integrating graphene/copper nanoparticle hybrid nanostructures. Nanoscale 9:19353–19359

    Article  CAS  Google Scholar 

  16. Rajbongshi BM, Verma A (2018) Plasmonic noble metal coupled biphasic TiO2 electrode for dye-sensitized solar cell. Mater Lett 232:220–223

    Article  CAS  Google Scholar 

  17. Guo LM, Liang K, Marcus K et al (2016) Enhanced photoelectrocatalytic reduction of oxygen using Au@TiO2 plasmonic film. ACS Appl Mater Interfaces 8:34970–34977

    Article  CAS  Google Scholar 

  18. Lee SH, Nishi H, Tatsuma T (2017) Tunable plasmon resonance of molybdenum oxide nanoparticles synthesized in non-aqueous media. Chem Commun 53:12680–12683

    Article  CAS  Google Scholar 

  19. Khojasteh H, Salavati-Niasari M, Sangsefidi FS (2018) Photocatalytic evaluation of RGO/TiO2NWs/Pd–Ag nanocomposite as an improved catalyst for efficient dye degradation. J Alloy Compd 746:611–618

    Article  CAS  Google Scholar 

  20. Keihan AH, Hosseinzadeh R, Farhadian M, Kooshki H, Hosseinzadeh G (2016) Solvothermal preparation of Ag nanoparticle and graphene co-loaded TiO2 for the photocatalytic degradation of paraoxon pesticide under visible light irradiation. RSC Adv 6:83673–83687

    Article  CAS  Google Scholar 

  21. Wang QY, Zhong JS, Zhang M, Chen DQ, Ji ZG (2016) In situ fabrication of TiO2 nanotube arrays sensitized by Ag nanoparticles for enhanced photoelectrochemical performance. Mater Lett 182:163–167

    Article  CAS  Google Scholar 

  22. Ge MZ, Cao CY, Li SH et al (2016) In situ plasmonic Ag nanoparticle anchored TiO2 nanotube arrays as visible-light-driven photocatalysts for enhanced water splitting. Nanoscale 8:5226–5234

    Article  CAS  Google Scholar 

  23. Liu XH, Liu Y, Lu SY, Guo W, Xi BD (2018) Performance and mechanism into TiO2/Zeolite composites for sulfadiazine adsorption and photodegradation. Chem Eng J 350:131–147

    Article  CAS  Google Scholar 

  24. Cao M, Wang P, Ao Y, Wang C, Hou J, Qian J (2016) Visible light activated photocatalytic degradation of tetracycline by a magnetically separable composite photocatalyst: graphene oxide/magnetite/cerium-doped titania. J Colloid Interface Sci 467:129–139

    Article  CAS  Google Scholar 

  25. Lorencik S, Yu QL, Brouwers HJH (2016) Photocatalytic coating for indoor air purification: synergetic effect of photocatalyst dosage and silica modification. Chem Eng J 306:942–952

    Article  CAS  Google Scholar 

  26. Bian Z, Cao F, Zhu J, Li H (2015) Plant uptake-assisted round-the-clock photocatalysis for complete purification of aquaculture waste water using sunlight. Environ Sci Technol 49:2418–2424

    Article  CAS  Google Scholar 

  27. Hurtado L, Solis-Casados D, Escobar-Alarcon L, Romero R, Natividad R (2016) Multiphase photo-capillary reactors coated with TiO2 films: preparation, characterization and photocatalytic performance. Chem Eng J 304:39–47

    Article  CAS  Google Scholar 

  28. Chen LL, Li L, Wang TT, Zhang LY, Xing SX, Wang CG, Su ZM (2014) A novel strategy to fabricate multifunctional Fe3O4@C@TiO2 yolk-shell structures as magnetically recyclable photocatalysts. Nanoscale 6:6603–6608

    Article  CAS  Google Scholar 

  29. Lugo-Vega CS, Serrano-Rosales B, de Lasa H (2016) Immobilized particle coating for optimum photon and TiO2 utilization in scaled air treatment photo reactors. Appl Catal B 198:211–223

    Article  CAS  Google Scholar 

  30. Qian X, Ren M, Yue D, Zhu Y, Han Y, Bian Z, Zhao Y (2017) Mesoporous TiO2 films coated on carbon foam based on waste polyurethane for enhanced photocatalytic oxidation of VOCs. Appl Catal B 212:1–6

    Article  CAS  Google Scholar 

  31. Zhang L, Xing Z, Zhang H, Li Z, Wu X, Zhang X, Zhang Y, Zhou W (2016) High thermostable ordered mesoporous SiO2–TiO2 coated circulating-bed biofilm reactor for unpredictable photocatalytic and biocatalytic performance. Appl Catal B 180:521–529

    Article  CAS  Google Scholar 

  32. Liang M, Li W, Qi Q et al (2016) Catalyst for the degradation of 1,1-dimethylhydrazine and its by-product N-nitrosodimethylamine in propellant wastewater. RSC Adv 6:5677–5687

    Article  CAS  Google Scholar 

  33. Yu X, Liu J, Yu Y, Zuo S, Li B (2014) Preparation and visible light photocatalytic activity of carbon quantum dots/TiO2 nanosheet composites. Carbon 68:718–724

    Article  CAS  Google Scholar 

  34. Zhou W, Sasaki S, Kawasaki A (2014) Effective control of nanodefects in multiwalled carbon nanotubes by acid treatment. Carbon 78:121–129

    Article  CAS  Google Scholar 

  35. Chen J, Cui X, Zhu Y, Jiang W, Sui K (2017) Design of superior conductive polymer composite with precisely controlling carbon nanotubes at the interface of a co-continuous polymer blend via a balance of π–π interactions and dipole–dipole interactions. Carbon 114:441–448

    Article  CAS  Google Scholar 

  36. Jbeli A, Hamden Z, Bouattour S et al (2018) Chitosan–Ag–TiO2 films: an effective photocatalyst under visible light. Carbohyd Polym 199:31–40

    Article  CAS  Google Scholar 

  37. Peng C, Wang W, Zhang W, Liang Y, Zhuo L (2017) Surface plasmon-driven photoelectrochemical water splitting of TiO2 nanowires decorated with Ag nanoparticles under visible light illumination. Appl Surf Sci 420:286–295

    Article  CAS  Google Scholar 

  38. Shao J, Sheng W, Wang M, Li S, Chen J, Zhang Y, Cao S (2017) In situ synthesis of carbon-doped TiO2 single-crystal nanorods with a remarkably photocatalytic efficiency. Appl Catal B 209:311–319

    Article  CAS  Google Scholar 

  39. He D, Li Y, Wang I, Wu J, Yang Y, An Q (2017) Carbon wrapped and doped TiO2 mesoporous nanostructure with efficient visible-light photocatalysis for NO removal. Appl Surf Sci 391:318–325

    Article  CAS  Google Scholar 

  40. Cui Y, Ma Q, Deng X et al (2017) Fabrication of Ag–Ag2O/reduced TiO2 nanophotocatalyst and its enhanced visible light driven photocatalytic performance for degradation of diclofenac solution. Appl Catal B 206:136–145

    Article  CAS  Google Scholar 

  41. Lakshmana Reddy N, Kumar S, Krishnan V, Sathish M, Shankar MV (2017) Multifunctional Cu/Ag quantum dots on TiO2 nanotubes as highly efficient photocatalysts for enhanced solar hydrogen evolution. J Catal 350:226–239

    Article  Google Scholar 

  42. Barrientos L, Allende P, Laguna-Bercero MA, Pastrián J, Rodriguez-Becerra J, Cáceres-Jensen L (2018) Controlled Ag–TiO2 heterojunction obtained by combining physical vapor deposition and bifunctional surface modifiers. J Phys Chem Solids 119:147–156

    Article  CAS  Google Scholar 

  43. Ye J, Cheng H, Li H et al (2017) Highly synergistic antimicrobial activity of spherical and flower-like hierarchical titanium dioxide/silver composites. J Colloid Interface Sci 504:448–456

    Article  CAS  Google Scholar 

  44. Zhang J, Liu X, Suo X, Li P, Liu B, Shi H (2017) Facile synthesis of Ag/AgCl/TiO2 plasmonic photocatalyst with efficiently antibacterial activity. Mater Lett 198:164–167

    Article  CAS  Google Scholar 

  45. Zhao J, Li WJ, Fan LP, Quan Q, Wang JF, Xiao CF (2019) Yolk-porous shell nanospheres from siliver-decorated titanium dioxide and silicon dioxide as an enhanced visible-light photocatalyst with guaranteed shielding for organic carrier. J Colloid Interface Sci 534:480–489

    Article  CAS  Google Scholar 

  46. Hernandez JV, Coste S, Murillo AG, Romo FC, Kassiba A (2017) Effects of metal doping (Cu, Ag, Eu) on the electronic and optical behavior of nanostructured TiO2. J Alloy Compd 710:355–363

    Article  Google Scholar 

  47. Yang C, Zhang X, Qin J, Shen X, Yu R, Ma M, Liu R (2017) Porous carbon-doped TiO2 on TiC nanostructures for enhanced photocatalytic hydrogen production under visible light. J Catal 347:36–44

    Article  CAS  Google Scholar 

  48. Ko S, Banerjee C, Sankar J (2011) Photochemical synthesis and photocatalytic activity in simulated solar light of nanosized Ag doped TiO2 nanoparticle composite. Compos B 42:579–583

    Article  Google Scholar 

  49. Jiang Z, Wei W, Mao D, Chen C, Shi Y, Lv X, Xie J (2015) Silver-loaded nitrogen-doped yolk–shell mesoporous TiO2 hollow microspheres with enhanced visible light photocatalytic activity. Nanoscale 7:784–797

    Article  CAS  Google Scholar 

  50. Yan X, Wang XY, Gu W et al (2015) Single-crystalline AgIn(MoO4)2 nanosheets grafted Ag/AgBr composites with enhanced plasmonic photocatalytic activity for degradation of tetracycline under visible light. Appl Catal B 164:297–304

    Article  CAS  Google Scholar 

  51. Luo BF, Xu DB, Li D, Wu GL, Wu MM, Shi WD, Chen M (2015) Fabrication of a Ag/Bi3TaO7 plasmonic photocatalyst with enhanced photocatalytic activity for degradation of tetracycline. ACS Appl Mater Interfaces 7:17061–17069

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the Natural Science Foundation of Jiangsu Province (No. BK20131226), the National Natural Science Foundation of China (Nos. 51273171, 51673090), and a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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YZ, MG, and XL was involved in experimentation and drafting of the manuscript. LJ, ZY, and XZ reviewed the manuscript and analyzed the data.

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Correspondence to Lijun Ji.

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Zhang, Y., Gong, M., Liu, X. et al. Preparation of activated carbon nanotube foams loaded with Ag-doped TiO2 for highly efficient photocatalytic degradation under UV and visible light. J Mater Sci 54, 2975–2989 (2019). https://doi.org/10.1007/s10853-018-3089-3

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