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Journal of Industrial and Engineering Chemistry, Vol.10, No.6, 911-916, 2004  Cyclopolymerization of 4-Dipropargylamino-4'-nitroazobenzene by Transition Metal Catalysts
Polymer Chemistry Laboratory, College of General Education, Kyungil University, Kyungsangbuk-Do 712-701, Korea
1Department of Chemistry, School of Education, Pusan National University, Pusan 609-735, Korea
2Electronic Materal Research Center, LG. Chem, Yusong-Gu, Daejeon 305-380, Korea
3Zenphotonics, Rm 303, K-MAC BLD., 104-11 Moonji-Dong, Yusong-Gu, Daejeon 305-380, Korea
4Department of Environ. & Applied Chem. Engineering, Kangnung National University, Gangneung 210-702, Korea
5Division of Image and Information Engineering, Pukyong National University, Busan 608-739, Korea
The cyclopolymerization of 4-dipropargylamino-4'-nitroazobenzene, a dipropargyl monomer having azo and nitro functional groups, was performed using palladium, platium, and ruthenium chlorides. The polymerization by these catalysts proceeded well to give high yields of polymer. However, the resulting polymers were generally insoluble in organic solvents, although the polymerization had proceeded in a homogeneous manner during the reaction process. The polymer structure was characterized, by solid-state 13C-NMR and IR spectroscopy and elemental analysis, to have a conjugated polymer backbone system. The thermal and morphological properties were also measured and are discussed.
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[Referenced By]
- Gal YS, Jin SH, Gui TL, Lee WC, Yun NG, Park SH, Lee SS, Bae JS, Journal of Industrial and Engineering Chemistry, 11(3), 432, 2005
- Gal YS, Jin SH, Lim KT, Lee WC, Journal of Industrial and Engineering Chemistry, 11(4), 603, 2005
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