|
그래핀 및 그래핀 기반 나노복합체의 에너지저장소자용 전극 특성
Electrode Properties of Graphene and Graphene-Based Nanocomposites for Energy Storage Devices
김광만†, 이영기, 김상욱  1한국전자통신연구원 융합부품소재연구부문 전력제어소자팀, 305-700 대전광역시 유성구 가정로 138
1한국과학기술원 신소재공학과, 305-701 대전광역시 유성구 과학로 335 Kwang Man Kim†, Young-Gi Lee, and Sang Ouk Kim1 Research Team of Power Control Devices, Electronics & Telecommunications Research Institute (ETRI), 138 Gwahak-ro, Yuseong-gu, Daejeon 305-700, Korea
1Department of Material Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), 335 Gwahak-ro, Yuseong-gu, Daejeon 305-701, Korea
초록
그래핀(graphene)은 sp2 탄소원자들이 벌집 격자를 이룬 형태의 2차원 나노시트를 의미하며, 높은 비표면적(이론치 2600 m2 g-1)과 우수한 전기전도도(전형치 8×10^(5) S cm-1) 및 기계적 강도로 인해 리튬이온전지의 음전극 활물질 및 초고용량 커패시터의 전극 활물질로서 사용 가능성이 높아지고 있다. 본 총설에서는 현재까지 알려진 그래핀 나노시트와 그래핀을 기반으로 하는 나노복합체의 제조법을 소개하고, 이를 리튬이온전지와 초고용량 커패시터의 전극소재로 적용하였을 때의 특성을 그 나노구조적 관점과 연관하여 논의하였다.
Graphene is a two-dimensional nanosheet consisting of honeycomb lattices of sp2 carbon atoms. It is one of promising active materials for the anode of lithium-ion battery and the electrode of supercapacitor, due to its large specific surface area(theoretically 2600 m2 g-1), high electric conductivity(typically 8×10^(5) S cm-1), and mechanical strength. In this review, the synthetic methods of graphene nanosheet and graphene-based nanocomposite are introduced.
Also, the electrochemical properties obtainable when the graphene-based materials are adopted to the electrodes of lithium-ion battery and supercapacitor are discussed along with their nanostructures.
[References]
- Sato K, Noguchi M, Demachi A, Oki N, Endo M, Science, 264(5158), 556, 1994
- Kaskhedikar NA, Maier J, Adv. Mater., 21(25-26), 2664, 2009
- Liang MH, Luo B, Zhi LJ, Int. J. Energy Res., 33(13), 1161, 2009
- Liang M, Zhi L, J. Mater. Chem., 19, 5871, 2009
- Pumera M, Chem. Record, 9, 211, 2009
- Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA, Science, 306, 666, 2004
- McAllister MJ, Li JL, Adamson DH, Schniepp HC, Abdala AA, Liu J, Herrera-Alonso M, Milius DL, Car R, Prud’homme RK, Aksay IA, Chem. Mater., 19, 4396, 2007
- Si Y, Samulski ET, Chem. Mater., 20, 6792, 2008
- Kane CL, Nature, 438, 168, 2005
- Yoo E, Kim J, Hosono E, Zhou H, Kudo T, Honma I, Nano Lett., 8, 2277, 2008
- Mukhopadhyay I, Hoshino N, Kawasaki S, Okino F, Hsu WK, Touhara H, J. Electrochem. Soc., 149(1), A39, 2002
- Takamura T, Endo K, Fu L, Wu Y, Lee KJ, Matsumoto T, Electrochim. Acta, 53(3), 1055, 2007
- Gautier S, Leroux F, Frackowiak E, Faugere AM, Rouzaud JN, Beguin F, J. Phys. Chem. A, 105(24), 5794, 2001
- Suzuki T, Hasegawa T. Mukai SR, Tamon H, Carbon, 41, 1933, 2003
- Li D, Muller MB, Gilje S, Kaner RB, Wallace GG, Nature Nanotech., 3, 101, 2008
- Li D, Kaner RB, Science, 320, 1170, 2008
- Wang C, Li D, Too CO, Wallace GG, Chem. Mater., 21, 2604, 2009
- Wang G, Shen X, Yao J, Park J, Carbon, 47, 2049, 2009
- Guo P, Song H, Chen X, Electrochem. Commun., 11, 1320, 2009
- Pan D, Wang S, Zhao B, Wu M, Zhang H, Wang Y, Jiao Z, Chem. Mater., 21, 3136, 2009
- Wang X, Zeng Z, Ahn H, Wang G, Appl. Phys. Lett., 95, 183103, 2009
- Wang G, Wang B, Wang X, Park J, Dou S, Ahn H, Kim K, J. Mater. Chem., 19, 8378, 2009
- Chou SL, Wang JL, Choucair M, Liu HK, Stride JA, Dou SX, Electrochem. Commun., 12, 303, 2010
- Liu X, Hu YS, Muller JO, Schlogl R, Maier J, Su DS, Chem Sus Chem, in press., 3, 2010
- Murugan AV, Muraliganth T, Manthiram A, Chem. Mater., 21, 5004, 2009
- Wang D, Choi D, Li J, Yang Z, Nie Z, Kou R, Hu D, Wang C, Saraf LV, Zhang J, Aksay IA, Liu J, ACS Nano, 3, 907, 2009
- Choi D, Wang D, Viswanathan VV, Bae IT, Wang W, Nie Z, Zhang JG, Graff GL, Liu J, Yang Z, Duong T, Electrochem. Commun., in press., 12, 2010
- Paek SM, Yoo E, Honma I, Nano Lett., 9, 72, 2009
- Yao J, Shen X, Wang B, Liu H, Wang G, Electrochem. Commun., 11, 1849, 2009
- Yang S, Cui G, Pang S, Cao Q, Kolb U, Fang X, Maier J, Mullen K, ChemSus Chem., in press., 3, 2010
- Xu C, Wang X, Yang L, Wu Y, J. Solid-State Chem., 182, 2486, 2009
- Ji F, Li YL, Feng JM, Su D, Wen YY, Feng Y, Hou F, J. Mater. Chem., 19, 9063, 2009
- Ding Y, Jiang Y, Xu F, Yin J, Ren H, Zhou Q, Long Z, Zhang P, Electrochem. Commun., 12, 10, 2010
- Yang CK, Appl. Phys. Lett., 94, 163115, 2009
- Choucair M, Thordarson P, Stride JA, Nature Nanotech., 4, 30, 2009
- Zhu Z, Su D, Weinberg G, Jentoft RE, Schlogl R, Small, 1, 107, 2005
- Murugan AV, Muraliganth T, Manthiram A, J. Phys. Chem., C112, 14665, 2008
- Wang DW, Li F, Zhao J, Ren W, Chen ZG, Tan J, Wu ZS, Gentle I, Lu GQ, Cheng HM, ACS Nano, 3, 1745, 2009
- Stoller MD, Park S, Zhu Y, An J, Ruoff RS, Nano Lett., 8, 3498, 2008
- Wang Y, Shi Z, Huang Y, Ma Y, Wang C, Chen M, Chen Y, J. Phys. Chem., C113, 13103, 2009
- Chen Y, Zhang X, Yu P, Ma YW, J. Power Sources, 195(9), 3031, 2010
- Li F, Song J, Yang H, Gan S, Zhang Q, Han D, Ivaska A, Niu L, Nanotechnology, 20, 455602, 2009
About CrossRef  CrossRef is an independent membership association, founded and directed by publishers. CrossRef’s mandate is to connect users to primary research content, by enabling publishers to do collectively what they can’t do individually. CrossRef is also the official DOI registration agency for scholarly and professional publications. It operates a cross-publisher citation linking system that allows a researcher to click on a reference citation on one publisher’s platform and link directly to the cited content on another publisher’s platform, subject to the target publisher’s access control practices. CrossRef’s citation-linking network today covers millions of articles and other content items from several hundred scholarly and professional publishers.
|
