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Journal of Industrial and Engineering Chemistry, Vol.11, No.6, 797-817, 2005  Preparation of Novel Porous Carbons Supporting Metal Nanoparticles and their Applications to Energy and Environment Related Issues
Department of Chemical Engineering, Kyoto University, Kyoto 615-8510, Japan
A new method for preparing novel porous carbons supporting metal nano-particles is introduced. The method just carbonizes certain types of ion exchange resins after exchanging them with various cations. Three applications of this method to energy and environment related issues are introduced in this review. The first application is the preparation of molecular sieving carbon in which it is shown that the pore distribution is controlled in the range of 0.35 to 0.45 nm in diameter by choosing cation types and carbonization conditions. The second application is the use of the Ni/carbon as a catalyst. It is shown that NO is decomposed to N2 at as low as 300 ℃ by use of the Ni/Carbon. It is also shown that the Ni/Carbon is successfully utilized to gasify organic compounds dissolving in water under hydrothermal conditions, producing fuel gas consisting of H2 and CH4. The success of the second application is due to high dispersion of a large amount of Ni nanoparticles within porous carbon. The third application of the method is the preparation of a magnetic targeted carrier for drug delivery. It is shown that the Co/Carbon has magnetic properties well usable as the magnetic targeted carrier.
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