화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.46, 426-435, February, 2017
Stearic acid hydrodeoxygenation over Pd nanoparticles embedded in mesoporous hypercrosslinked polystyrene
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Stearic acid hydrodeoxygenation into n-heptadecane on the catalyst containing Pd nanoparticles incorporated in the hypercrosslinked polystyrene matrix was studied. The used catalysts were characterized using TEM, CO chemisorption, low-temperature nitrogen physisorption and XPS. A clear hydrogen pressure dependent induction period was noticed. Kinetic regularities were studied for the indicated reaction in the presence of polymer based catalysts. A mathematical model for decarboxylation was suggested which was able to adequately describe experimental data at different temperatures, hydrogen pressures and initial concentrations of stearic acid. Kinetic constants were calculated and their statistical analysis was performed.
  1. Deneyer A, Renders T, Van Aelst J, Van den Bosch S, Gabrie D, Sels BF, Curr. Opin. Chem. Biol., 29, 40 (2015)
  2. Kukushkin RG, Bulavchenko OA, Kaichev VV, Yakovlev VA, Appl. Catal. B: Environ., 163(-), 531 (2015)
  3. Hermida L, Abdullah AZ, Mohamed AR, Renew. Sust. Energ. Rev., 42, 1223 (2015)
  4. Kumar P, Yenumala SR, Maity SK, Shee D, Appl. Catal. A: Gen., 471(-), 28 (2014)
  5. Ma B, Zhao C, Green Chem., 17, 1692 (2015)
  6. Meller E, Green U, Aizenshtat Z, Sasson Y, Fuel, 133(-), 89 (2014)
  7. Shao Y, Xia Q, Liu X, Lu G, Wang Y, ChemSusChem, 8, 1761 (2015)
  8. Srifa A, Viriya-Empikul N, Assabumrungrat S, Faungnawakij K, Catal. Sci. Technol., 5, 3693 (2015)
  9. Mahfud FH, van Geel FP, Venderbosch RH, Heeres HJ, Sep. Sci. Technol., 43(11-12), 3056 (2008)
  10. Luo J, Xu Y, Zhao LJ, Dong LL, Tong DM, Zhu LF, Hu CW, Bioresour. Technol., 101(22), 8873 (2010)
  11. Xu JM, Jiang JC, Sun YJ, Lu YJ, Biomass Bioenerg., 32(11), 1056 (2008)
  12. Elliott DC, Hart TR, Energy Fuels, 23(1), 631 (2009)
  13. Donnis B, Egeberg RG, Blom P, Knudsen KG, Top. Catal., 52, 229 (2009)
  14. Arun N, Sharma RV, Dalai AK, Renew. Sust. Energ. Rev., 48, 240 (2015)
  15. Liu QY, Bie YW, Qiu SB, Zhang Q, Sainio J, Wang TJ, Ma LL, Lehtonen J, Appl. Catal. B: Environ., 147(-), 236 (2014)
  16. Kubickova I, Snare M, Eranen K, Maki-Arvela P, Murzin DY, Catal. Today, 106(1-4), 197 (2005)
  17. Snare M, Kubickova I, Maki-Arvela P, Eranen K, Murzin DY, Ind. Eng. Chem. Res., 45(16), 5708 (2006)
  18. Maki-Arvela P, Kubickova I, Snare M, Eranen K, Murzin DY, Energy Fuels, 21(1), 30 (2007)
  19. Peng B, Yao Y, Zhao C, Lercher JA, Angew. Chem.-Int. Edit., 51, 2072 (2012)
  20. Zhao C, Lercher JA, Angew. Chem.-Int. Edit., 124, 1 (2012)
  21. Srifa A, Faungnawakij K, Itthibenchapong V, Assabumrungrat S, Chem. Eng. J., 278(-), 249 (2015)
  22. Hachemi I, Jenistova K, Maki-Arvela P, Kumar N, Eranen K, Hemming J, Murzin D, Catal. Sci. Technol., 6, 1476 (2016)
  23. Santillan-Jimenez E, Morgan T, Shoup J, Harman-Ware AE, Crocker M, Catal. Today, 237(-), 136 (2014)
  24. Kubicka D, Horacek J, Setnicka M, Bulanek R, Zukal A, Kubickova I, Appl. Catal. B: Environ., 145(-), 101 (2014)
  25. Jeczmionek L, Porzycka-Semczuk K, Fuel, 128(-), 296 (2014)
  26. Chen H, Wang QF, Zhang XW, Wang L, Fuel, 159(-), 430 (2015)
  27. Yang YH, Wang QF, Chen H, Zhang XW, Fuel, 133(-), 241 (2014)
  28. Huang Z, Ding S, Li Z, Lin HI, Li F, Li L, Zhong Z, Gao C, Chen C, Li Y, Int. J. Hydrog. Energy, 41, 16402 (2016)
  29. Galadima A, Muraza O, J. Ind. Eng. Chem., 29(-), 12 (2015)
  30. Fan CY, Zeng YH, Do DD, Nicholson D, Chem. Eng. Sci., 121(-), 313 (2015)
  31. Kon K, Onodera W, Takakusagia S, Shimizu K, Catal. Sci. Technol, 4, 3705 (2014)
  32. Matthias KH, Pfutzenreuter AR, Hoelderich WF, Appl. Catal. B: Environ., 174-175, 383 (2015)
  33. Hollak SAW, Arins MA, de Jong KP, van Es DS, ChemSusChem, 7, 1057 (2014)
  34. Dragu A, Kinayyigit S, Garcia-Suarez EJ, Florea M, Stepan E, Velea S, Tanase L, Colliere V, Philippot K, Granger P, Parvulescu VI, Appl. Catal. A: Gen., 504(-), 81 (2015)
  35. de Sousa FP, Cardoso CC, Pasa VMD, Fuel Process. Technol., 143(-), 35 (2016)
  36. Song W, Zhao C, Lercher JA, Chem.-Eur. J., 19, 9833 (2013)
  37. Immer JG, Kelly MJ, Lamb HH, Appl. Catal. A: Gen., 375(1), 134 (2010)
  38. Huber GW, O'Connor P, Corma A, Appl. Catal. A: Gen., 329(-), 120 (2007)
  39. Doluda VY, Sulman EM, Matveeva VG, Sulman MG, Bykov AV, Lakina NV, Sidorov AI, Valetsky PM, Bronstein LM, Top. Catal., 56, 688 (2013)
  40. Sulman EM, Valetsky PM, Sulman MG, Bronstein LM, Sidorov AI, Doluda VY, Matveeva VG, Chem. Eng. Process., 50(10), 1041 (2011)
  41. Sulman EM, Doluda VY, Matveeva VG, Sulman MG, Catal. Ind., 4, 55 (2007)
  42. Matveeva VG, Valetsky PM, Sulman MG, Bronshtein LM, Sidorov AI, Doluda VY, Gavrilenko AV, Nikoshvili LZ, Bykov AV, Grigorjev MV, Sulman EM, Catal. Ind., 3, 260 (2011)
  43. Stepacheva AA, Nikoshvili LZ, Sulman EM, Matveeva VG, Green Process. Synth., 3, 441 (2014)
  44. Canton P, Fagherazzi G, Battagliarin M, Menegazzo F, Pinna F, Pernicone N, Langmuir, 18(17), 6530 (2002)
  45. Wagner D, Riggs WM, Davis LE, Moulder JF, Muilenberg GE, Handbook of X-ray Photoelectron Spectroscopy, Perkin-Elmer Corporation, Eden Prairie, MN, 1979.
  46. NIST X-ray Photoelectron Spectroscopy Database, Version 3.5, National Institute of Standards and Technology, Gaithersburg, 2003. http://srdata.nist.gov/xps/.
  47. Penner S, Bera P, Pedersen S, Ngo LT, Harris JJW, Campbell CT, J. Phys. Chem. B, 110(48), 24577 (2006)
  48. Gregg SJ, Sing KSW, Adsorption, Surface Area and Porosity, 2nd ed., Academic Press, London, 1982.
  49. IUPAC Recommendation, Pure Appl. Chem., 66, 1739 (1994)
  50. Simakova I, Simakova O, Maki-Arvela P, Simakov A, Estrada M, Murzin DY, Appl. Catal. A: Gen., 355(1-2), 100 (2009)
  51. Sun K, Wilson AR, Thompson ST, Lamb HH, ACS Catal., 5, 1939 (2015)
  52. Lugo-Jose YK, Monnier JR, Heyden A, Williams CT, Catal. Sci. Technol., 4, 3909 (2014)
  53. Sun KY, Schulz TC, Thompson ST, Lamb HH, Catal. Today, 269(-), 93 (2016)
  54. Haario H, ModEst, Parameter estimation and optimization software, Helsinki, 2007.