화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.46, 212-221, February, 2017
Synthesis/characterization of molecular imprinted polymer based on magnetic chitosan/graphene oxide for selective separation/ preconcentration of fluoxetine from environmental and biological samples
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A novel molecular imprinted polymer (MIP) as a SPE sorbent was synthesized for fluoxetine through a coprecipitation method. The synthesized polymer was characterized by Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). The kinetic and adsorption equilibrium was studied. Quantification of fluoxetine was done based on the competitive inclusion complex formation of fluoxetine with phenolphthalein-β-cyclodextrin using fiber optic linear array spectrophotometry. The method exhibited a linear dynamic range of 0.8-10.0 μg L-1 with a detection limit of 0.03 μg L-1 and a preconcentration factor of 500. The developed method was successfully applied to determine fluoxetine in various samples.
  1. Benfield P, Heel R, Lewis S, Drugs, 32, 481 (1986)
  2. Rossi A, Barraco A, Donda P, Ann. Gen. Hosp. Psychiatry, 3, 1 (2004)
  3. Bagheri H, Zandi O, Aghakhani A, Anal. Chim. Acta, 692, 80 (2011)
  4. Barclay VKH, Tyrefors NL, Johansson IM, Pettersson CE, J. Chromatogr. A, 1227, 105 (2012)
  5. Raggi MA, Mandrioli R, Casamenti G, Volterra V, Desiderio C, Fanali S, Chromatographia, 50, 423 (1999)
  6. Unceta N, Go´ mez-Caballero A, Sa´nchez A, Milla´ n S, Sampedro MC, Goicolea MA, Salle´ s J, Barrio RJ, J. Pharm. Biomed. Anal., 46, 763 (2008)
  7. Demeestere K, Petrovic M, Gros M, Dewulf J, Van Langenhove H, Barcelo D, Anal. Bioanal. Chem., 396, 825 (2010)
  8. Queiroz MEC, Oliveira EB, Breton F, Pawliszyn J, J. Chromatogr. A, 1174, 72 (2007)
  9. Chaves AR, Moura BHF, Caris JA, Rabelo D, Queiroz MEC, J. Chromatogr. A, 1399, 1 (2015)
  10. Alizadeh R, Najafi NM, Poursani EMA, J. Pharm. Biomed. Anal., 70, 492 (2012)
  11. Nevado JJB, Llerena MJV, Cabanillas CG, Robledo VR, Buitrago S, J. Sep. Sci., 29, 103 (2006)
  12. Shamsipur M, Dastjerdi LS, Haghgoo S, Armspach D, Matt D, Aboul-Enein HY, Anal. Chim. Acta, 601, 130 (2007)
  13. Mandrioli R, Pucci V, Visini D, Varani G, Raggi MA, J. Pharm. Biomed. Anal., 29, 1127 (2002)
  14. Atta-Politou J, Skopelitis I, Apatsidis I, Koupparis M, Eur. J. Pharm. Sci., 12, 311 (2001)
  15. Shah CR, Shah NJ, Suhagia BN, Patel NM, J. AOAC Int., 90, 1573 (2007)
  16. Darwish IA, Abdine HH, Amer SM, Al-Rayes LI, Int. J. Anal. Chem., 2009, 1 (2009)
  17. Bigdelifam D, Mirzaei M, Hashemi M, Amoli-Diva M, Rahmani O, Zohrabi P, Taherimaslak Z, Turkjokar M, Anal. Methods, 6, 8633 (2014)
  18. Kazemi E, Shokoufi N, Shemirani F, Chem. Spec. Bioavailab., 23, 249 (2011)
  19. Raggi MA, Bugamelli F, Casamenti G, Mandrioli R, De Ronchi D, Volterra V, J. Pharm. Biomed. Anal., 18, 699 (1998)
  20. Fernandes C, Jiayu P, Sandra P, Lancas FM, Chromatographia, 64, 517 (2006)
  21. Zorita S, Martensson L, Mathiasson L, J. Sep. Sci., 30, 2513 (2007)
  22. Dadfarnia S, Shabani AMH, Kazemi E, Khormizi SAH, Tammadon F, J. Braz. Chem. Soc., 26, 1180 (2015)
  23. Kazemi E, Shabani AMH, Dadfarnia S, Microchim. Acta, 182, 1025 (2015)
  24. Yang DH, Shin MJ, Kim M, Kim YD, Kim H, Shin JS, Microchim. Acta, 183, 1601 (2016)
  25. Gao L, Chen L, Li X, Microchim. Acta, 182, 781 (2014)
  26. Qiu H, Luo C, Sun M, Lu F, Fan L, Li X, Carbon, 50, 4052 (2012)
  27. Li Y, Li X, Dong C, Qi J, Han X, Carbon, 48, 3427 (2010)
  28. Xie C, Zhang Z, Wang D, Guan G, Gao D, Liu J, Anal. Chem., 78, 8339 (2006)
  29. Qiu H, Luo C, Sun M, Lu F, Fan L, Li X, Anal. Chim. Acta, 744, 75 (2012)
  30. Peeters M, Kobben S, Jime´nez-Monroy KL, Modesto L, Kraus M, Vandenryt T, Gaulke A, van Grinsven B, Ingebrandt S, Junkers T, Wagner P, Sens. Actuators B-Chem., 203, 527 (2014)
  31. Ning F, Peng H, Li J, Chen L, Xiong H, J. Agric. Food. Chem., 62, 7436 (2014)
  32. Guibal E, Sep. Purif. Technol., 38(1), 43 (2004)
  33. Chatterjee S, Lee MW, Woo SH, Bioresour. Technol., 101(6), 1800 (2010)
  34. Guo TY, Xia YQ, Wang J, Song MD, Zhang BH, Biomaterials, 26, 5737 (2005)
  35. Wang Y, Wang E, Wu Z, Li H, Zhu Z, Zhu X, Dong Y, Carbohydr. Polym., 101, 517 (2014)
  36. Zhang YL, Zhang J, Dai CM, Zhou XF, Liu SG, Carbohydr. Polym., 97, 809 (2013)
  37. Deng P, Xu Z, Kuang Y, Food Chem., 157, 490 (2014)
  38. Han D, Yan L, Chen W, Li W, Carbohydr. Polym., 83, 653 (2011)
  39. Duan H, Li L, Wang X, Wang Y, Li J, Luo C, RSC Adv., 5, 68397 (2015)
  40. Afkhami A, Madrakian T, Khalafi L, Chem. Pharm. Bull., 54, 1642 (2006)
  41. Tahmasebi E, Yamini Y, Anal. Chim. Acta, 756, 13 (2012)
  42. Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)
  43. Kazemi E, Dadfarnia S, Shabani AMH, Talanta, 141, 273 (2015)
  44. Travlou NA, Kyzas GZ, Lazaridis NK, Deliyanni EA, Langmuir, 29(5), 1657 (2013)
  45. Liu B, Han M, Guan G, Wang S, Liu R, Zhang Z, J. Phys. Chem., 115, 17320 (2011)
  46. Huamin Q, Lulu F, Li X, Li L, Min S, Chuannan L, Carbohydr. Polym., 92, 394 (2013)
  47. Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)
  48. Dadfarnia S, Shabani AMH, Moradi SE, Emami S, Appl. Surf. Sci., 330(-), 85 (2015)
  49. Akhtar M, Bhanger MI, Iqbal S, Hasany SM, J. Hazard. Mater., 128(1), 44 (2006)
  50. Cheung WH, Szeto YS, McKay G, Bioresour. Technol., 98(15), 2897 (2007)
  51. Ozacar M, Sengil IA, Process Biochem., 40(2), 565 (2005)