화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.46, 91-102, February, 2017
Interior design engineering of CuS architecture alteration with rise in reaction bath temperature for high performance symmetric flexible solid state supercapacitor
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Present work portrays surface morphology alteration of CuS thin film with increase in reaction bath temperature. The porous nanoflowers like morphology of CuS offers higher electron transfer and shorten ion diffusion pathway, which facilitates transfer of electrolyte ions. Nanoflowers like morphology of CuS electrode exhibits specific capacitance (Cs) of 1818.2 F g-1 at scan rate of 5 mV s-1 with electrochemical cycling stability of 92%. The symmetric FSS-SCs-PVA-LiClO4 device demonstrates Cs of 172.5 F g-1, specific power density of 1750 W kg-1 and capacity retention of 93% after 2000 CV cycles. More importantly, this device glows the panel of 200 red LEDs.
  1. Chen S, Zhu J, Wu X, Han Q, Wang X, ACS Nano, 4, 2822 (2010)
  2. Guo CX, Li CM, Energy Environ. Sci., 4, 4504 (2011)
  3. Zhi M, Xiang C, Li J, Li M, Wu N, Nanoscale, 5, 72 (2013)
  4. Meng C, Liu C, Chen L, Hu C, Fan S, Nano Lett., 10, 4025 (2010)
  5. Simon P, Gogotsi Y, Nat. Mater., 7(11), 845 (2008)
  6. Zhang Y, Feng H, Wu XB, Wang LZ, Zhang AQ, Xia TC, Dong HC, Li XF, Zhang LS, Int. J. Hydrog. Energy, 34(11), 4889 (2009)
  7. Hahn M, Barbieri O, Gallay R, Kotz R, Carbon, 44, 2523 (2006)
  8. Lee HY, Kim SW, Lee HY, Electrochem. Solid State Lett., 4(3), A19 (2001)
  9. Wang HL, Casalongue HS, Liang YY, Dai HJ, J. Am. Chem. Soc., 132(21), 7472 (2010)
  10. Liu JP, Jiang J, Cheng CW, Li HX, Zhang JX, Gong H, Fan HJ, Adv. Mater., 23(18), 2076 (2011)
  11. Kim YT, Tadai K, Mitani T, J. Mater. Chem., 15, 4914 (2015)
  12. Cherusseri J, Kar KK, J. Mater. Chem. A, 3, 21586 (2015)
  13. Lu X, Yu M, Wang G, Tong Y, Li Y, Energy Environ. Sci., 7, 2160 (2014)
  14. Zhang L, Zhu P, Zhou F, Zeng W, Su H, Li G, Gao J, Sun R, Wong CP, ACS Nano, 10, 1273 (2016)
  15. Gund GS, Dubal DP, Chodankar NR, Cho JY, Romero PG, Park C, Lokhande CD, Sci. Rep., 5, 12454 (2015)
  16. Hassan S, Suzuki M, El-Moneim AA, Am. J. Mater. Sci., 2, 11 (2012)
  17. Jiang J, Liu J, Ding R, Ji X, Hu Y, Li X, Hu A, Wu F, Zhu Z, Huang X, J. Phys. Chem., 114, 929 (2010)
  18. Wang Q, Wang X, Liu B, Yu G, Hou X, Chen D, Shen G, J. Mater. Chem. A, 1, 2468 (2013)
  19. Peng Z, Lin J, Ye R, Samuel ELG, Tour JM, ACS Appl. Mater. Interfaces, 7, 3414 (2015)
  20. Gund GS, Dubal DP, Jambure SB, Shinde SS, Lokhande CD, J. Mater. Chem. A, 1, 4793 (2013)
  21. Wang YB, Zhang LX, Jiu HF, Li N, Sun YX, Appl. Surf. Sci., 303(-), 54 (2014)
  22. Mary KA, Unnikrishnan NV, Philip R, Physica E, 74, 151 (2015)
  23. Liu XM, Ai LH, Jiang J, Powder Technol., 283(-), 539 (2015)
  24. Ren HT, Xu WC, Zhu SL, Cui ZD, Yang XJ, Inoue A, Electrochim. Acta, 190(-), 221 (2016)
  25. Wu C, Yu SH, Chen S, Liu G, Liu B, J. Mater. Chem., 16, 3326 (2006)
  26. Lu YY, Zhang YY, Zhang J, Shi Y, Li Z, Feng ZC, Li C, Appl. Surf. Sci., 370(-), 312 (2016)
  27. Zhang J, Feng H, Qin Q, Zhang G, Cui Y, Chai Z, Zheng W, J. Mater. Chem. A, 4, 6357 (2016)
  28. Deng C, Ge X, Hu H, Yao L, Han C, Zhao D, CrystEngComm, 16, 2738 (2014)
  29. Xu H, Hu X, Yang H, Sun Y, Hu C, Huang Y, Adv. Eng. Mater., 140188 (2014)
  30. Qian L, Tian X, Yang L, Mao J, Yuan H, Xiao D, RSC Adv., 3, 1703 (2013)
  31. Bulakhe RN, Sahoo S, Nguyen TT, Lokhande CD, Roh C, Lee YR, Shim JJ, RSC Adv., 6, 14844 (2016)
  32. Xu PP, Miao CX, Cheng K, Ye K, Yin JL, Cao DX, Pan ZC, Wang GL, Zhang XF, Electrochim. Acta, 214(-), 276 (2016)
  33. Raj CJ, Kim BC, Cho WJ, Lee WG, Seo Y, Yu KH, J. Alloy. Compd., 586, 191 (2015)
  34. Lei Z, Christov N, Zhao XS, Energy Environ. Sci., 4, 1866 (2011)
  35. Patil AM, Lokhande VC, Lokhande AC, Chodankar NR, Ji T, Kim JH, Lokhande CD, RSC Adv., 6, 68388 (2016)
  36. Chen Q, Li X, Zang X, Cao Y, He Y, Li P, Wang K, Wei J, Wu D, Zhu H, RSC Adv., 4, 36253 (2014)
  37. Chodankar NR, Dubal DP, Lokhande AC, Lokhande CD, J. Colloid Interface Sci., 460(-), 370 (2015)
  38. Krishnamoorthy K, Pazhamalai P, Veerasubramani GK, Kim SJ, J. Power Sources, 321(-), 112 (2016)
  39. Tao HC, Zhu SC, Yang XL, Zhang LL, Ni SB, Electrochim. Acta, 190(-), 168 (2016)
  40. Krishnamoorthy K, Veerasubramani GK, Rao AN, Kim SJ, Mater. Res. Express, 1, 035006 (2014)
  41. Huang KJ, Zhang JZ, Xing K, Electrochim. Acta, 149(-), 28 (2014)
  42. Zhou K, Liang J, Liu J, Sun P, Bu J, Zhang W, Chen G, RSC Adv., 6, 16832 (2016)
  43. Peng H, Ma G, Sun K, Mu J, Wang H, Lei Z, J. Mater. Chem. A, 2, 3303 (2014)
  44. Wang K, Zhao C, Zhang Z, Min S, Qian X, RSC Adv., 6, 16963 (2016)
  45. Zhu T, Xi B, Zhou L, Lou XW, J. Mater. Chem., 22, 7851 (2012)
  46. Shi C, Dong H, Zhu R, Li H, Sun Y, Xu D, Zhao Q, Yu D, Nano Energy, 13, 670 (2015)
  47. Hsu YK, Chen YC, Lin YG, Electrochim. Acta, 139(-), 401 (2014)
  48. Huang KJ, Zhang JZ, Fan Y, J. Alloy. Compd., 625, 158 (2015)
  49. Zhang J, Feng H, Yang J, Qin Q, Fan H, Wei C, Zheng W, ACS Appl. Mater. Interfaces, 7, 21735 (2015)
  50. Shen L, Yu L, Wu HB, Yu XY, Zhang X, Lou XW, Nat. Commun., 6, 1 (2015)
  51. Patil AM, Lokhande AC, Chodankar NR, Kumbhar VS, Lokhande CD, Mater. Des., 97, 407 (2016)
  52. Dubal DP, Dhawale DS, Gujar TP, Lokhande CD, Appl. Surf. Sci., 257(8), 3378 (2011)
  53. Shinde SK, Dubal DP, Ghodake GS, Kim DY, Fulari VJ, J. Electroanal. Chem., 732(-), 80 (2014)
  54. Sankapal BR, Gajare HB, Dubai DP, Gore RB, Salunkhe RR, Ahn H, Chem. Eng. J., 247(-), 103 (2014)
  55. Deshmukh PR, Pusawale SN, Jagadale AD, Lokhande CD, J. Mater. Sci., 47(3), 1546 (2012)